Transactions of the Materials Research Society of Japan
Online ISSN : 2188-1650
Print ISSN : 1382-3469
ISSN-L : 1382-3469
Regular Papers
Benzo-fused BODIPY Derivative as a Fluorescent Chemosensor for Fe3+, Cu2+, and Al3+
Jun KawakamiYuta SasakiKoji YanaseShunji Ito
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2019 Volume 44 Issue 2 Pages 69-73

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Abstract

The compound (5-(3,5-dimethyl)pyrrol-2-yl)-3-(4-(dimethylamino)styryl)-1,7-dimethyl benzo-fused BODIPY (BFBODIPY-DMP-DMAS) was synthesized and investigated as a fluorescent chemosensor for metal ions. We explored the metal-ion recognition of BFBODIPY-DMP-DMAS in separate acetonitrile solutions of Mg2+, Ca2+, Ba2+, Fe2+, Fe3+, Co2+, Ni2+, Cu2+, Ag+, Zn2+, Cd2+, Al3+, and Pb2+. Mg2+, Ca2+, Ba2+, Fe2+, Co2+, Ni2+, Ag+, Zn2+, Cd2+, and Pb2+ did not affect the shape or intensity of the fluorescence spectra of the chemosensor. However, the sensor fluorescence was shifted to shorter wavelengths for Al3+ and quenched for Fe3+ and Cu2+.

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© 2019 The Materials Research Society of Japan
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