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Vol. 26 No. 24 (2014)

Copyright (c) 2014 Yikai Yu1, Liping Deng3, Meihua Yu3

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Design and Controlled-Synthesis of Novel Slightly Crosslinked and Reactive Polycationic Dye-Fixatives for Cotton Fabric

https://doi.org/10.14233/ajchem.2014.17088
Yikai Yu1
1College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P.R. China 2Key Laboratory of Chemical Biology of Jiangxi Province, Nanchang 330022, P.R. China 3Jiangxi Vocational and Technical College of Information Application, Nanchang 330043, China *Corresponding author: E-mail: yuyikai1980@163.com
Liping Deng3
1College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P.R. China 2Key Laboratory of Chemical Biology of Jiangxi Province, Nanchang 330022, P.R. China 3Jiangxi Vocational and Technical College of Information Application, Nanchang 330043, China *Corresponding author: E-mail: yuyikai1980@163.com
Meihua Yu3
1College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P.R. China 2Key Laboratory of Chemical Biology of Jiangxi Province, Nanchang 330022, P.R. China 3Jiangxi Vocational and Technical College of Information Application, Nanchang 330043, China *Corresponding author: E-mail: yuyikai1980@163.com

Corresponding Author(s) : Yikai Yu1

Asian Journal of Chemistry, Vol. 26 No. 24 (2014)

Abstract

New series of slightly crosslinked and reactive polycationic dye-fixatives for cotton fabric were synthesized by copolymerization of 3-chloro-2-hydroxypropyltriallyl-ammonium chloride (CHTAAC) and dimethyldiallylammonium chloride. The structures of obtained dye-fixatives could be controlled by varying molar ratios of raw-materials of CHTAAC to DMDAAC during polymerization and their molecular weights were possibly controlled by adjusting different polymerization conditions. The results showed, under the same conditions that the polymerization temperatures were kept at 60 °C for 6 h and then heated to 70 °C for 2 h, when the initial monomer concentrations (w/w) were increased from 40 to 52.5 % and the initiator amount were gradually decreased from 9 to 5 %, a series of slightly crosslinked and reactive polycationic dye-fixatives with 1-5 % molar contents of triallylmethylammonium chloride (TAMAC) units in main chains and controlled intrinsic viscosities of 0.16-0.75 dL/g were successfully synthesized, which were as designed and could be expected as novel useful dye-fixatives for cotton fabric.

Keywords

Controlled synthesis 3-Chloro-2-hydroxypropyltriallyl-ammonium chloride Dimethyldiallylammonium chloride.
Yu1, Y., Deng3, L., & Yu3, M. (2014). Design and Controlled-Synthesis of Novel Slightly Crosslinked and Reactive Polycationic Dye-Fixatives for Cotton Fabric. Asian Journal of Chemistry, 26(24), 8344–8348. https://doi.org/10.14233/ajchem.2014.17088
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