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Mechanical strength of PET fibers treated in cold plasma and thermal exposed

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Abstract

As a followup to previous work, experiments with argon and oxygen Radio Frequency plasma treated polyethylene terepthalate (PET) exposed to 100 °C after cold plasma treatment were performed. Tensile tests results in monofilaments treated in oxygen and argon plasma for 5 s, 20 s, 30 s, and 100 s showed a decrease in the average tensile strength compared with the untreated fibers. It was also observed that the reduction in mechanical strength is more significant for argon plasma and very sensitive to the treatment time for oxygen plasma. Experimental data obtained from tensile tests in samples thermal exposed to 100 °C after plasma treatments indicate the same influence of treatment times on mechanical strength, as observed for cold plasma treated fibers. Furthermore, an increase in tensile strength when compared with the samples unexposed to 100 °C was observed. Scanning electron microscopy, used to analyze effects of cold plasma treatment on fibers surfaces, indicates differences in roughness profiles depending on the type of treatment. The distance of roughness interval, Dri, was a parameter introduced to relate the fibers surface condition and average tensile strength. Statistical analysis of experimental data was performed to explain influences of treatment time, and environmental and temperature effects on mechanical properties.

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References

  1. S. Weidner, G. Kühn, R. Decker, D. Roessner, and J. Friedrich: “Influence of Plasma Treatment on the Molar Mass of Poly(Ethylene Terephtalate) Investigate by Different Chromatographic and Spectroscopy Methods,” J. Appl. Polym. Sci.: Part A: Polym. Chem., 1998, 36, pp. 1639–48.

    Article  CAS  Google Scholar 

  2. S.A.C. Gould, D.A. Schiraldi, and M.L. Occelli: “Analysis of Poly(ethylene terephthalate) (PET) Films by Atomic Force Microscopy,” J. Appl. Polym. Sci., 1998, 67(7), pp. 1237–43.

    Article  Google Scholar 

  3. P.J. Herrera-Franco and L.T. Drzal: “Comparison of Methods for the Measurement,” Composites, 1992, 23(1), pp. 2–27.

    Article  CAS  Google Scholar 

  4. A. Teishevand and A. Maron: “The Effect of Transcrystallinity on the Transverse Mechanical Properties of Single-Polymer Polyethylene Composites,” J. Appl. Polym. Sci., 1995, 56, pp. 959–66.

    Article  Google Scholar 

  5. K.A. Kodokian and A.J. Kinloch: “Surface Pretreatment and Adhesion of Thermoplastics Fibre Composites,” J. Mater. Sci., 1988, 7, pp. 625–27.

    CAS  Google Scholar 

  6. L.Y. Yuan, S.S. Shyu, and J.Y. Lai: “Plasma Surface Treatment of Carbon Fibers. Part 2: Interfacial Adhesion With Poly (Phenylene Sulfide),” Comp. Sci. Technol., 1992, 45, pp. 9–16.

    Article  CAS  Google Scholar 

  7. G. Kill, D.H. Hunter, and N.S. McIntyre: “Reactions of Polyethylene Surface With the Downstream Products of an Air Plasma: Gas Phase and Surface Spectroscopic Studies,” J. Polym. Sci.: Part A Polym. Chem., 1996, 34, pp. 2299–310.

    Article  CAS  Google Scholar 

  8. N.K Anifantis, P.A. Kakavas, and G.C. Papanicolaou: “Thermal Concentration Due to Imperfect Adhesion in Fiber-Reinforced Composites,” Comp. Sci. Technol., 1997, 57, pp. 687–96.

    Article  CAS  Google Scholar 

  9. W.G. Pitt, J.E. Lakenan, and A.B. Strong: “The Influence of Plasma Gas Species on the Adhesion of Thermoplastic to Organic Fibers,” J. Appl. Polym. Sci., 1993, 48, pp. 845–56.

    Article  CAS  Google Scholar 

  10. B.R.K. Blackman, A.J. Kinloch, and J.F. Watts: “The Plasma Treatment of Thermoplastics Fibre Composites for Adhesive Bonding,” Composites, 1994, 25(5), pp. 332–41.

    Article  CAS  Google Scholar 

  11. B.Z. Jang: “Control of Interfacial Adhesion in Continuous Carbon and Kevlar Fiber Reinforced Polymer Composites,” Comp. Sci. Technol., 1992, 44, pp. 333–49.

    Article  CAS  Google Scholar 

  12. S. Gao and Y. Zeng: “Surface Modification of Ultrahigh Molecular Weight Polyethylene Fibers by Plasma Treatment,” J. Appl. Polym. Sci., 1993, 47, pp. 2065–71.

    Article  CAS  Google Scholar 

  13. D. Ferrante, S. Iannace, and T. Monetta: “Mechanical Strength of Cold Plasma PET Fibers,” J. Mater. Sci., 1998, 33, pp. 1–5.

    Google Scholar 

  14. B. Chapman: “Glow Discharge Processes—Sputtering and Plasma Etching,” John Wiley & Sons, New York, NY, 1980, pp. 177–343.

    Google Scholar 

  15. E. Occhiello, M. Morra, G.L. Guerrini, and F. Garbassi: “Adhesion Properties of Plasma-Treated Carbon/PEEK Composites,” Composites, 1992, 23(3), pp. 193–200.

    Article  CAS  Google Scholar 

  16. M.O.H. Cioffi, H.J.C. Voorwald, V. Ambrogi, T. Monetta, F. Bellucci, and L. Nicolais: “Tensile Strength of Radio Frequency Cold Plasma Treated PET Fibers. Part I: Influence of Environment and Treatment Time,” J. Mater. Eng. Perf., 2002, 11(6), pp. 659–66.

    Article  CAS  Google Scholar 

  17. T. Tanaka, H. Nakayama, A. Sakaida, and T. Imamichi: “Evaluation of Weibull Parameters for Static Strengths of Ceramics by Monte Carlo Simulation,” Mater. Sci. Res. Int., 1995, 1(1), pp. 51–58.

    Google Scholar 

  18. C. Lipson and N.J. Sheth: “Statistical Distribution” in Statistical Design and Analysis of Engineering Experiments, McGraw Hill, NY, 1973, pp. 36–45.

    Google Scholar 

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Cioffi, M.O.H., Voorwald, H.J.C., Ambrogi, V. et al. Mechanical strength of PET fibers treated in cold plasma and thermal exposed. J. of Materi Eng and Perform 12, 279–287 (2003). https://doi.org/10.1361/105994903770343123

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  • DOI: https://doi.org/10.1361/105994903770343123

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