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Publicly Available Published by De Gruyter January 1, 2009

Nickel-catalyzed coupling reactions of alkenes

  • Sze-Sze Ng , Chun-Yu Ho , Kristin D. Schleicher and Timothy F. Jamison

Abstract

Several reactions of simple, unactivated alkenes with electrophiles under Ni(0) catalysis are discussed. The coupling of olefins with aldehydes and silyl triflates provides allylic or homoallylic alcohol derivatives, depending on the supporting ligands and, to a lesser extent, the substrates employed. Reaction of alkenes with isocyanates yields N-alkyl acrylamides. In these methods, alkenes act as the functional equivalents of alkenyl- and allylmetal reagents.


Conference

International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-14), International Symposium on Organometallic Chemistry Directed Toward Organic Synthesis, OMCOS, Organometallic Chemistry Directed Toward Organic Synthesis, 14th, Nara, Japan, 2007-08-02–2007-08-06


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Published Online: 2009-01-01
Published in Print: 2008-01-01

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