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Publicly Available Published by De Gruyter January 1, 2009

Chemistry of tetrathiomolybdate and tetraselenotungstate: Applications in carbohydrate chemistry

  • Perali Ramu Sridhar , V. Saravanan and S. Chandrasekaran

Abstract

An efficient one pot synthesis of thio and selenolevoglucosans from 1,6-diactivated carbohydrate derivatives has been achieved using benzyltriethylammonium tetrathiomolybdate, [BnNEt3]2MoS4, as a sulfur transfer reagent and tetraethylammonium tetraselenotungstate, [Et4N]2WSe4, as a selenium transfer reagent, respectively. The methodology has also been extended to the synthesis of 1,5-epithio and 1,5-episeleno pentoses.


Conference

International Symposium on the Chemistry of Natural Products and the 4th International Congress on Biodiversity, International Conference on Biodiversity, International Symposium on the Chemistry of Natural Products, ICOB, ISCNP, Biodiversity, Natural Products, 24th, Delhi, India, 2004-01-26–2004-01-31


Published Online: 2009-01-01
Published in Print: 2005-01-01

© 2013 Walter de Gruyter GmbH, Berlin/Boston

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