Abstract
A furofuran annulation/oxidative rearrangement strategy was used to construct the basic skeleton of the pyranonaphthoquinone family of antibiotics. This synthetic methodology has been applied to the synthesis of the spiroacetal-containing pyranonaphthoquinone antibiotic griseusin A, to an analog of the C-glycoside medermycin, and to a dimeric pyranonaphthoquinone.
Conference
International Conference on Organic Synthesis (ICOS-13), International Conference on Organic Synthesis, ICOS, Organic Synthesis, 13th, Warsaw, Poland, 2000-07-01–2000-07-05
Published Online: 2009-01-01
Published in Print: 2000-01-01
© 2013 Walter de Gruyter GmbH, Berlin/Boston