Recent design tools for tuning the properties of conjugated polymers for efficient polymer solar cells (PSCs) are briefly reviewed. Based on limitations in the solar-to-electric energy conversion process imposed by material properties, recent research has focused on lowering the highest occupied molecular orbital (HOMO) level, reducing the bandgap, and controlling the molecular conformation and donor–acceptor phase separation. Additionally, the stability of PSCs can be improved through molecular design. Finally, a few less-conventional material design strategies for device improvement through polymer–polymer blends and triplet utilization are introduced. Molecular design has been an invaluable tool in controlling these material properties.
References
1 W. Cai, X. Gong, Y. Cao. Sol. Energy Mater. Sol. Cells94, 114 (2010). 10.1016/j.solmat.2009.10.005Search in Google Scholar
2 H. J. Park, M. G. Kang, S. H. Ahn, L. J. Guo. Adv. Energy Mater.22, E247 (2010). 10.1002/adma.201000250Search in Google Scholar PubMed
3 10.1039/b9nr00430k, F. C. Krebs, T. Tromholt, M. Jørgensen. Nanoscale2, 873 (2010).Search in Google Scholar PubMed
4 10.1364/OE.18.00A272, A. J. Medford, M. R. Lilliedal, M. Jørgensen, D. Aarø, H. Pakalski, J. Fyenbo, F. C. Krebs. Opt. Expr.18, A272 (2010).Search in Google Scholar PubMed
5 10.1039/b823001c, F. C. Krebs, S. A. Gevorgyan, J. Alstrup. J. Mater. Chem.19, 5442 (2009).Search in Google Scholar
6 New polymers push Solarmer’s OPV efficiency to record 8.13 %, http://www.pv-tech.org/news/_a/new_polymers_push_solarmers_opv_efficiency_to_record_8.13/ (accessed July 2010).Search in Google Scholar
7 10.1016/j.solmat.2008.01.004, J. A. Hauch, P. Schilinsky, S. A. Choulis, R. Childers, M. Biele, C. J. Brabec. Sol. Energy Mater. Sol. Cells92, 727 (2008).Search in Google Scholar
8 10.1021/jp075565x, I. W. Hwang, D. Moses, A. J. Heeger. J. Phys. Chem. C112, 4350 (2008).Search in Google Scholar
9 10.1021/nl9038289, R. A. Marsh, J. M. Hodgkiss, S. Albert-Seifried, R. H. Friend. Nano Lett.10, 923 (2010).Search in Google Scholar PubMed
10 10.1002/pip.791, A. Pivrikas, N. S. Sariciftci, G. Juska, R. Osterbacka. Prog. Photovolt.: Res. Appl.15, 677 (2007).Search in Google Scholar
11 10.1002/adma.200800982, P. E. Shaw, A. Ruseckas, I. D. W. Samuel. Adv. Mater.20, 3516 (2008).Search in Google Scholar
12 10.1021/cm049654n, K. M. Coakley, M. D. McGehee. Chem. Mater.16, 4533 (2004).Search in Google Scholar
13 10.1126/science.270.5243.1789, G. Yu, J. Gao, J. C. Hummelen, F. Wudl, A. J. Heeger. Science270, 1789 (1995).Search in Google Scholar
14 10.1002/adma.200800606, Y. Li, Y. Zou. Adv. Mater.20, 2952 (2008).Search in Google Scholar
15 10.1039/b819210c, H. A. Becerril, N. Miyaki, M. L. Tang, R. Mondal, Y. S. Sun, A. C. Mayer, J. E. Parmer, M. D. McGehee, Z. Bao. J. Mater. Chem.19, 591 (2009).Search in Google Scholar
16 10.1021/am900155y, M. S. Kim, B. G. Kim, J. Kim. Appl. Mater. Interfaces1, 1264 (2009).Search in Google Scholar PubMed
17 10.1021/ja9066139, F. Huang, K. S. Chen, H. L. Yip, S. K. Hau, O. Acton, Y. Zhang, J. Luo, A. K. Y. Jen. J. Am. Chem. Soc.131, 13886 (2009).Search in Google Scholar PubMed
18 L. Huo, J. Hou, S. Zhang, H. Y. Chen, Y. Yang. Angew. Chem.122, 1542 (2010). 10.1002/ange.200906934Search in Google Scholar
19 10.1016/j.solmat.2009.12.013, S. H. Kim, I. W. Hwang, Y. Jin, S. Song, J. Moon, H. Suh, K. Lee. Sol. Energy Mater. Sol. Cells (2010).Search in Google Scholar
20 10.1002/adma.200800606, Y. Li, Y. Zou. Adv. Mater.20, 2952 (2008).Search in Google Scholar
21 10.1021/ja808373p, Y. Liang, Y. Wu, D. Feng, S. T. Tsai, H. J. Son, G. Li, L. Yu. J. Am. Chem. Soc.131, 56 (2009).Search in Google Scholar PubMed
22 10.1146/annurev.physchem.54.011002.103811, B. J. Schwartz. Annu. Rev. Phys. Chem.54, 141 (2003).Search in Google Scholar PubMed
23 10.1021/jp807065a, J. Lee, H. J. Kim, T. Chen, K. Lee, K. S. Kim, S. C. Glotzer, J. Kim, N. A. Kotov. J. Phys. Chem. C113, 109 (2009).Search in Google Scholar
24 10.1038/nmat1574, Y. Kim, S. Cook, S. Tuladhar, S. A. Choulis, J. Nelson, J. R. Durrant, D. C. Bradley, M. Giles, I. McCulloch, C. S. Ha, M. Ree. Nat. Mater.5, 197 (2006).Search in Google Scholar
25 10.1002/adma.200803700, B. Lim, K. J. Baeg, H. G. Jeong, J. Jo, H. Kim, J.-W. Park, Y. Y. Noh, D. Vak, J. H. Park, J.-W. Park, D. Y. Kim. Adv. Mater.21, 2808 (2009).Search in Google Scholar
26 10.1021/ja9057986, R. Qin, W. Li, C. Li, C. Du, C. Veit, H. F. Schleiermacher, M. Andersson, Z. Bo, Z. Liu, O. Inganas, U. Wuerfel, F. Zhang. J. Am. Chem. Soc.131, 14612 (2009).Search in Google Scholar PubMed
27 10.1021/am900327n, S. Xiao, A. C. Stuart, S. Liu, W. You. Appl. Mater. Interfaces1, 1613 (2009).Search in Google Scholar PubMed
28 C. Y. Yu, B. T. Ko, C. Ting, C. P. Chen. Sol. Energy Mater. Sol. Cells93, 6113 (2009). 10.1016/j.solmat.2008.12.017Search in Google Scholar
29 10.1103/PhysRevB.67.064203, P. J. Brown, D. S. Thomas, A. Kohler, J. S. Wilson, J. S. Kim, C. M. Ramsdale, H. Sirringhaus, R. H. Friend. Phys. Rev. B67, 064203 (2003).Search in Google Scholar
30 10.1038/nmat1612, I. McCulloch, M. Heeney, C. Bailer, K. Genevicius, I. MacDonald, M. Shkunov, D. Sparrowe, S. Tierney, R. Wagner, W. Zhang, M. L. Chabinyc, R. J. Kline, M. D. McGehee, M. F. Toney. Nat. Mater.5, 328 (2006).Search in Google Scholar PubMed
31 10.1016/j.polymer.2010.05.015, W. Li, R. Qin, Y. Zhou, M. Andersson, F. Li, C. Zhang, B. Li, Z. Bo, F. Zhang. Polymer51, 3031 (2010).Search in Google Scholar
32 10.1002/adma.200600160, D. Mühlbacher, M. Scharber, M. Morana, Z. Zhu, D. Waller, R. Gaudiana, C. Brabec. Adv. Mater.18, 2884 (2006).Search in Google Scholar
33 10.1021/ma061760i, K. Colladet, S. Fourier, T. J. Cleij, L. Lutsen, J. Gelan, D. Vanderzande, L. H. Nguyen, H. Neugebauer, S. Sariciftci, A. Aguirre, G. Janssen, E. Goovaerts. Macromolecules40, 65 (2007).Search in Google Scholar
34 10.1038/nphoton.2009.192, H. Y. Chen, J. Kou, S. Zhang, Y. Liang, G. Yang, Y. Yang, L. Yu, Y. Wu, G. Li. Nat. Phot.3, 649 (2009).Search in Google Scholar
35 10.1021/ja101888b, Y. Zou, A. Najari, P. Berrouard, S. Beaupré, B. R. A?ch, Y. Tao, M. Leclerc. J. Am. Chem. Soc.132, 5330 (2010).Search in Google Scholar PubMed
36 10.1016/j.solmat.2008.01.005, M. Jørgensen, K. Norrman, F. C. Krebs. Sol. Energy Mater. Sol. Cells92, 686 (2008).Search in Google Scholar
37 10.1021/cm051320q, F. C. Krebs, H. Spanggard. Chem. Mater.17, 5235 (2005).Search in Google Scholar
38 10.1039/b516086c, F. Guo, Y. G. Kim, J. R. Reynolds, K. S. Schanze. Chem. Commun.17, 1887 (2006).Search in Google Scholar PubMed
39 10.1063/1.3082081, M. Arif, K. Yang, L. Li, P. Yu, S. Guha, S. Gangopadhyay, M. Forster, U. Scherf. Appl. Phys. Lett.94, 063307 (2009).Search in Google Scholar
40 10.1039/b616996a, O. Bolton, J. Kim. J. Mater. Chem.17, 1981 (2007).Search in Google Scholar
41 Z. Zhu, D. Mühlbacher, M. Morana, M. Koppe, M. C. Scharber, D. Waller, G. Dennler, C. J. Brabec. “Design rules for efficient organic solar cells”, in High-Efficient Low-Cost Photovoltaics, Vol. 140, pp. 195–222, Springer, Berlin/Heidelberg (2009). 10.1007/978-3-540-79359-5_13Search in Google Scholar
42 10.1002/adma.200501717, M. C. Scharber, D. Mühlbacher, M. Koppe, P. Denk, C. Waldauf, A. J. Heeger, C. J. Brabec. Adv. Mater.18, 789 (2006).Search in Google Scholar
43 10.1038/nmat2548, K. Vandewal, K. Tvingstedt, A. Gadisa, O. Inganas, J. V. Manca. Nat. Mater.8, 904 (2009).Search in Google Scholar PubMed
44 10.1021/ja9007722, M. D. Perez, C. Borek, S. R. Forrest, M. E. Thompson. J. Am. Chem. Soc.131, 9281 (2009).Search in Google Scholar PubMed
45 10.1021/cm100417z, Y. Zhang, S. K. Hau, H. L. Yip, Y. Sun, O. Acton, A. K. Y. Jen. Chem. Mater.22, 2696 (2010).Search in Google Scholar
46 10.1002/adma.200903528, Y. Liang, Z. Xu, J. Xia, S. T. Tsai, Y. Wu, G. Li, C. Ray, L. Yu. Adv. Mater.22, E135 (2010).Search in Google Scholar PubMed
47 10.1002/adma.200304150, M. Svensson, F. Zhang, S. C. Veenstra, W. J. H. Verhees, J. C. Hummelen, J. M. Kroon, O. Inganas, M. R. Andersson. Adv. Mater.15, 988 (2003).Search in Google Scholar
48 10.1016/j.solener.2003.08.039, C. A. Gueymard. Sol. Energy76, 423 (2004).Search in Google Scholar
49 10.1039/b306630d, C. Winder, N. S. Sariciftci. J. Mater. Chem.14, 1077 (2004).Search in Google Scholar
50 10.1021/cr950257t, J. Roncali. Chem. Rev.97, 173 (1997).Search in Google Scholar PubMed
51 10.1007/BF00558045, E. E. Havinga, W. Hoeve, H. Wynberg. Polym. Bull.29, 119 (1992).Search in Google Scholar
52 10.1021/am1000344, H. Zhou, L. Yang, S. Stoneking, W. You. Appl. Mater. Interfaces2, 1377 (2010).Search in Google Scholar PubMed
53 10.1021/ja0771989, N. Blouin, A. Michaud, D. Gendron, S. Wakim, E. Blair, R. Neagu-Plesu, M. Belletête, G. Durocher, Y. Tao, M. Leclerc. J. Am. Chem. Soc.130, 732 (2008).Search in Google Scholar PubMed
54 10.1016/j.eurpolymj.2010.05.001, F. Shi, G. Fang, F. Liang, L. Wang, Z. Mu, X. Zhang, Z. Xie, Z. Su. Eur. Polym. J.46, 1770 (2010).Search in Google Scholar
55 10.1103/PhysRevB.75.115327, B. P. Rand, D. P. Burk, S. R. Forrest. Phys. Rev. B75, 115327 (2007).Search in Google Scholar
56 10.1063/1.1650878, A. Gadisa, M. Svensson, M. R. Andersson, O. Inganas. Appl. Phys. Lett.84, 1609 (2004).Search in Google Scholar
57 10.1016/j.solmat.2008.09.022, T. Yamanari, T. Taima, J. Sakai, K. Saito. Sol. Energy Mater. Sol. Cells93, 759 (2009).Search in Google Scholar
58 10.1063/1.1620683, V. D. Mihailetchi, P. W. M. Blom, J. C. Hummelen, M. T. Rispens. J. Appl. Phys.94, 6849 (2003).Search in Google Scholar
59 10.1021/ma902197a, J. Hou, T. L. Chen, S. Zhang, L. Huo, S. Sista, Y. Yang. Macromolecules42, 9217 (2009).Search in Google Scholar
60 10.1016/j.solmat.2009.12.028, S. Berson, S. Cecioni, M. Billon, Y. Kervella, R. de Bettignies, S. Bailly, S. Guillerez. Sol. Energy Mater. Sol. Cells94, 699 (2010).Search in Google Scholar
61 10.1063/1.2836266, E. Wang, L. Wang, L. Lan, C. Luo, W. Zhuang, J. Peng, Y. Cao. Appl. Phys. Lett.92, 033307 (2008).Search in Google Scholar
62 10.1021/ma970627a, M. Trznadel, A. Pron, M. Zagorska, R. Chrzaszcz, J. Pielichowski. Macromolecules31, 5051 (1998).Search in Google Scholar
63 10.1002/adma.200801283, G. Dennler, M. C. Scharber, C. J. Brabec. Adv. Mater.21, 1323 (2009).Search in Google Scholar
64 10.1038/nphoton.2009.69, S. H. Park, A. Roy, S. Beaupré, S. Cho, N. Coates, J. S. Moon, D. Moses, M. Leclerc, K. Lee, A. J. Heeger. Nat. Phot.3, 297 (2009).Search in Google Scholar
65 10.1021/ma035620+, X. Yang, J. K. J. van Duren, R. A. J. Janssen, M. A. J. Michels, J. Loos. Macromolecules37, 2151 (2004).Search in Google Scholar
66 10.1039/b510618b, H. Hoppe, N. S. Sariciftci. J. Mater. Chem.16, 45 (2006).Search in Google Scholar
67 10.1016/S1369-7021(07)70276-6, A. C. Mayer, S. R. Scully, B. E. Hardin, M. W. Rowell, M. D. McGehee. Mater. Today10, 28 (2007).Search in Google Scholar
68 10.1021/cr050149z, S. Günes, H. Neugebauer, N. S. Sariciftci. Chem. Rev.107, 1324 (2007).Search in Google Scholar PubMed
69 10.1021/jz100100p, R. Giridharagopal, D. S. Ginger. J. Phys. Chem. Lett.1, 1160 (2010).Search in Google Scholar
70 10.1021/ma0618732, X. Yang, J. Loos. Macromolecules40, 1353 (2007).Search in Google Scholar
71 10.1002/adma.200802854, L. Chen, Z. Hong, G. Li, Y. Yang. Adv. Mater.21, 1434 (2009).Search in Google Scholar
72 J. S. Kim, Y. Lee, J. H. Lee, J. H. Park, J. K. Kim, K. Cho. Adv. Mater.22, 1355 (2010). 10.1002/adma.200902803Search in Google Scholar PubMed
73 10.1063/1.2437100, S. S. Sun, C. Zhang, A. Ledbetter, S. Choi, K. Seo, C. E. Bonner, M. Drees, N. S. Sariciftci. Appl. Phys. Lett.90, 043117 (2007).Search in Google Scholar
74 10.1038/nmat2594, R. Q. Png, P. J. Chia, J. C. Tang, B. Liu, S. Sivaramakrishnan, M. Zhou, S. H. Khong, H. S. O. Chan, J. H. Burroughes, L. L. Chua, R. H. Friend, P. K. H. Ho. Nat. Mater.9, 152 (2010).Search in Google Scholar PubMed
75 10.1063/1.882522, F. S. Bates, G. H. Fredrickson. Phys. Today52, 32 (1999).Search in Google Scholar
76 10.1063/1.1320022, S. A. Jenekhe, S. Yi. Appl. Phys. Lett.77, 2635 (2000).Search in Google Scholar
77 10.1063/1.2772185, M. M. Mandoc, W. Veurman, J. Sweelssen, M. M. Koetse, P. W. M. Blom. Appl. Phys. Lett.91, 073518 (2007).Search in Google Scholar
78 10.1002/adma.200900783, C. R. McNeill, N. C. Greenham. Adv. Mater.21, 3840 (2009).Search in Google Scholar
79 10.1063/1.2176863, M. M. Koetse, J. Sweelssen, K. T. Hoekerd, H. F. M. Schoo, S. C. Veenstra, J. M. Kroon, X. Yang, J. Loos. Appl. Phys. Lett.88, 083504 (2006).Search in Google Scholar
80 10.1063/1.2738197, C. R. McNeill, A. Abrusci, J. Zaumseil, R. Wilson, M. J. McKiernan, J. H. Burroughes, J. J. M. Halls, N. C. Greenham, R. H. Friend. Appl. Phys. Lett.90, 193506 (2007).Search in Google Scholar
81 10.1002/adfm.200800182, C. R. McNeill, J. J. M. Halls, R. Wilson, G. L. Whiting, S. Berkebile, M. G. Ramsey, R. H. Friend, N. C. Greenham. Adv. Funct. Mater.18, 2309 (2008).Search in Google Scholar
82 10.1002/pip.796, S. C. Veenstra, J. Loos, J. M. Kroon. Prog. Photovolt.: Res. Appl.15, 727 (2007).Search in Google Scholar
83 10.1021/ja071760d, X. Zhan, Z. Tan, B. Domercq, Z. An, X. Zhang, S. Barlow, Y. Li, D. Zhu, B. Kippelen, S. R. Marder. J. Am. Chem. Soc.129, 7246 (2007).Search in Google Scholar PubMed
84 10.1063/1.3086307, R. Steyrleuthner, S. Bange, D. Neher. J. Appl. Phys.105, 064509 (2009).Search in Google Scholar
85 10.1038/nature07727, H. Yan, Z. Chen, Y. Zhang, C. Newman, J. R. Quinn, F. Dotz, M. Kastler, A. Facchetti. Nature457, 679 (2009).Search in Google Scholar PubMed
86 10.1016/j.orgel.2009.04.011, B. P. Rand, S. Schols, D. Cheyns, H. Gommans, C. Girotto, J. Genoe, P. Heremans, J. Poortmans. Org. Elec.10, 1015 (2009).Search in Google Scholar
87 10.1063/1.3257383, B. P. Rand, C. Girotto, A. Mityashin, A. Hadipour, J. Genoe, P. Heremans. Appl. Phys. Lett.95, 173304 (2009).Search in Google Scholar
88 10.1016/j.synthmet.2009.07.041, K. Yang, M. Arif, M. Forster, U. Scherf, S. Guha. Synth. Met.159, 2338 (2009).Search in Google Scholar
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