Abstract
A polymer structure and function of lignophenol was examined by various structural analysis of lignophenols fractionated with preparative SEC. The base unit of lignophenol is 1,1-bis (aryl) propane-2-O-aryl ether unit in all the molecular weight areas by NMR analysis. But the amounts of combined cresol and phenolic hydroxyl groups were increased with decreasing molecular weight of fractionated lignophenols. The protein-adsorbing capacities and thermoplastic property of fractionated lignophenols differed with the molecular weights.
Similar content being viewed by others
Article PDF
References
K. Freudenberg, Science, 148, 595 (1965).
T. Higuchi, J. Biochem., 45, 515 (1958).
D. A. Goring, in “Lignins: Occurrence, Formation, Structure and Reactions,” K. V. Sarkanen and C. H. Ludwing, Ed., Willey-Interscience, New York, 1971.
K. Freudenberg, Holzforschung, 18, 3 (1964).
J. W. Adams and M. W. Schoenherr, U.S. Patent 4303562 (1981).
H. Nimz, “Wood Addhes. Chem. Technol.,” A. Pizzi, Ed., Ch.5, Dekker, New York, 1983, p 245.
M. R. Clark and J. D. Dolenko, U.S. Patent 4113675 (1978).
P. C. Muller, S. S. Kelly, and W. G. Glasser, J. Adhes., 17, 185 (1984).
M. Funaoka and I. Abe, Tappi J., 72, 145 (1989).
M. Funaoka and S. Fukatsu, Holzforschung, 50, 245 (1996).
M. Funaoka, Polym. Int., 47, 277 (1998).
A. Björkman, Svensk Papperstidning, 59, 477 (1956).
Y. Nagamatsu and M. Funaoka, Sen-i-Gakkaishi, 57, 75 (2001).
M. Bradford, Anal. Biochem., 26, 248 (1976).
M. Funaoka, M. Matsubara, N. Seki, and S. Fukatsu, Biotechnol. Bioeng., 46, 545 (1995).
G. A. Erdtman and R. Sanden, Acta Chem. Scand., 22, 1187 (1968).
M. Funaoka, Macromol. Symp., 201, 213 (2003).
H. Hatakeyama, K. Iwashita, G. Meshitsuka, and J. Nakano, Mokuzai gakkaishi, 22, 618 (1975).
Y. Nakamoko and S. Ishida, Kobunshi Ronbunshu, 10, 151 (1984).
E. Haslam, Biochem. J., 139, 285 (1974).
M. Funaoka, H. Ioka, T. Hosho, and Y. Tanaka, J. Network polym. Jpn., 17, 121 (1996).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mikame, K., Funaoka, M. Polymer Structure of Lignophenol I —Structure and Function of Fractionated Lignophenol—. Polym J 38, 585–591 (2006). https://doi.org/10.1295/polymj.PJ2005142
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1295/polymj.PJ2005142