Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
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Copper-Mediated Conversion of Alkynes into Nitriles via Iodotriazoles
Ryosuke Kori, Keigo Murakami, Yoshitake Nishiyama, Tatsuya Toma, Satoshi Yokoshima
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Keywords: alkyne, azide, nitrile, copper, cycloaddition
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2021 Volume 69 Issue 3 Pages 278-280

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Abstract

We disclose our studies on a copper-mediated reaction of alkynes with trimethylsilyl azide to afford nitriles, and proposed a reaction mechanism, which involves an iodoalkyne and an iodotriazole as intermediates.

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