Modeling core-hole screening in core-excitation spectroscopies

, and

Published under licence by IOP Publishing Ltd
, , Citation E L Shirley et al 2005 Phys. Scr. 2005 31 DOI 10.1238/Physica.Topical.115a00031

1402-4896/2005/T115/31

Abstract

We consider screening of the core-hole potential experienced by the ejected electron in core-excitation processes. This potential affects near-edge structure strongly, but it appears difficult to consistently obtain reliable screened core-hole potentials without substantial computation. Screening effects have both atomic and solid-state (or molecular/cluster) contributions. We emphasize aspects that must be true of "correct" screening models, in an attempt to circumvent the need to carry out full-scale randomphase approximation (RPA) or self-consistent-field calculations of the screening. We present and discuss three spectra computed with RPA and model screened potentials, suggesting ideas to be considered in future work developing screening models.

Export citation and abstract BibTeX RIS

Please wait… references are loading.
10.1238/Physica.Topical.115a00031