范方宇, 李晗, 邢献军. 温度对玉米秸秆成型颗粒烘焙制备生物炭及其特性的影响[J]. 农业工程学报, 2019, 35(1): 220-226. DOI: 10.11975/j.issn.1002-6819.2019.01.027
    引用本文: 范方宇, 李晗, 邢献军. 温度对玉米秸秆成型颗粒烘焙制备生物炭及其特性的影响[J]. 农业工程学报, 2019, 35(1): 220-226. DOI: 10.11975/j.issn.1002-6819.2019.01.027
    Fan Fangyu, Li Han, Xing Xianjun. Effect of temperature on preparation and characteristics of corn straw pellets torrefaction biochar[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2019, 35(1): 220-226. DOI: 10.11975/j.issn.1002-6819.2019.01.027
    Citation: Fan Fangyu, Li Han, Xing Xianjun. Effect of temperature on preparation and characteristics of corn straw pellets torrefaction biochar[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2019, 35(1): 220-226. DOI: 10.11975/j.issn.1002-6819.2019.01.027

    温度对玉米秸秆成型颗粒烘焙制备生物炭及其特性的影响

    Effect of temperature on preparation and characteristics of corn straw pellets torrefaction biochar

    • 摘要: 采用低温烘焙技术制备玉米秸秆成型生物炭,可解决玉米秸秆带来的环境污染及资源浪费。研究以玉米秸秆成型颗粒为原料,利用固定床反应器,制备了不同烘焙温度(250~400 ℃)成型生物炭,采用元素分析、工业分析、能量产率、质量产率、机械性能、疏水性、红外光谱(Fourier transform infrared spectroscopy,FTIR)、扫描电镜(Scanning electron microscopy,SEM)、元素K含量等分析生物炭特性。随烘焙温度升高,热值增加,能量产率降低,400 ℃时,成型生物炭热值为21.86 MJ/kg,能量产率为50.17%。成型生物炭颗粒表面裂纹增多,机械性能降低,350 ℃烘焙成型生物炭(CSP350)机械性能好于400 ℃烘焙成型生物炭(CSP400),低于成型生物质颗。烘焙生物炭疏水性提升,可贮藏于室外。成型玉米秸秆经烘焙热解发生了脱水、脱羰基、脱甲基反应,纤维素、半纤维素热解剧烈,木质素开始热解。随温度升高,其孔径呈下降趋势,比表面积增大。结果表明,玉米秸秆成型烘焙生物炭可作为优质生物燃料,适宜制备温度为300~350 ℃。

       

      Abstract: Abstract: China is an agricultural country with huge corn planting area. According to data of the 2015 Statistical Yearbook of China, corn planting area was 37 million hectares in 2014, which produced about 225 million tons of corn stalk wastes. The large amount of corn stalk wastes are treated by incineration or landfill, resulting in serious environmental pollution and waste of resources. In order to solve these problems, curing molding, thermo-chemical conversion and biochemical conversion are used to prepare all kinds of biofuel (e.g. gas, bio-oil, and biochar). Preparation of biochar from corn straw pellets is an effective method by thermal conversion. The torrefaction is a mild pyrolysis mode between 200 and 350 ℃ which results in partial devolatilization of the solid biomass. Biochar pellets from the torrefaction technology have a considerable density, desirable hardness, and good hydrophobicity. Using biochar pellets reduces transport and investment costs for fuel storage and process feeding to greater extent than using biochar powder. Therefore, there are obvious advantages of lower equipment cost, simpler equipment system, and higher production efficiency when biomass pellets are pyrolyzed. In this paper, biochar pellets of corn straw were produced by the fixed bed pyrolysis at different temperature (250-400 ℃) at the heating rate of 10 ℃/min for a residence time of 30 min, with the N2 flow rate of 100 mL/min. Biochars were collected after the pyrolysis reaction, and their characteristics were analyzed. Characteristics of biochar pellets were analyzed by elemental analysis, proximate analysis, energy yield, mass yield, mechanical properties, hydrophobicity, FTIR, SEM and K contents. With the increase of torrefaction temperature, the O content decreased, and the C content increased. The results caused the higher heating value of biochar increased and the mass yield and energy yield decreased. At 400 ℃, the higher heating value and energy yield of biochar pellets were 21.86 MJ/kg, 50.17%, respectively. The surface cracks of biochar pellets increased and the mechanical properties were reduced. The mechanical properties of biaochar at 350 ℃(CSP350) were better than that of biaochar at 400℃(CSP400), which was lower than that the raw corn straw pellets. But the mechanical properties of biochar pellets could meet the requirement for the use of storage and transportation. Biochar pellets showed good hydrophobicity, which benefitted their storage in outsides. Moreover, biochar pellets will not decay and disperse during storage. Analysis of FTIR indicated that dehydration, decarbonylation and demethylation occurred during torrefaction process of corn straw pellets, the cellulose and hemicellulose should be basically finished, and lignin began to pyrolyze. Analysis of SEM and BET showed that the pore size decreased and the surface area increased with the increase of temperature. The K content in biochar increased from 1.68% of raw pellets to 3.12% of CSP400. This phenomenon has an adverse effect on the combustion of biochar pellets, which is easy to slag in combustion furnace. In conclusion, the results showed that biochar pellets from corn straw could be used as biofuel, and the optimum preparation temperature was 300-350 ℃.

       

    /

    返回文章
    返回