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Constraints on the Equations of State of stiff anisotropic minerals: rutile, and the implications for rutile elastic barometry

Published online by Cambridge University Press:  22 April 2019

Gabriele Zaffiro ,
Ross J. Angel Open the ORCID record for Ross J. Angel [Opens in a new window]  and
Matteo Alvaro
Gabriele Zaffiro
Affiliation:
Department of Earth and Environmental Sciences, University of Pavia, Via A. Ferrata, 1 I-27100, Pavia, Italy
Ross J. Angel*
Affiliation:
Department of Earth and Environmental Sciences, University of Pavia, Via A. Ferrata, 1 I-27100, Pavia, Italy
Matteo Alvaro
Affiliation:
Department of Earth and Environmental Sciences, University of Pavia, Via A. Ferrata, 1 I-27100, Pavia, Italy
*
*Author for correspondence: Ross J. Angel, Email: rossjohnangel@gmail.com
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Abstract

We present an assessment of the thermo-elastic behaviour of rutile based on X-ray diffraction data and direct elastic measurements available in the literature. The data confirms that the quasi-harmonic approximation is not valid for rutile because rutile exhibits substantial anisotropic thermal pressure, meaning that the unit-cell parameters change significantly along isochors. Simultaneous fitting of both the diffraction and elasticity data yields parameters of KTR0= 205.14(15) GPa, KSR0= 207.30(14) GPa, $K_{TR0}^{\prime} $= 6.9(4) in a 3rd-order Birch-Murnaghan Equation of State for compression, αV0= 2.526(16) × 10–5 K–1, Einstein temperature θE = 328(12) K, Anderson-Grüneisen parameter δT = 7.6(6), with a fixed thermal Grüneisen parameter γ = 1.4 to describe the thermal expansion and variation of bulk modulus with temperature at room pressure. This Equation of State fits all of the available data up to 7.3 GPa at room temperature, and up to 1100 K at room pressure within its uncertainties. We also present a series of formulations and a simple protocol to obtain thermodynamically consistent Equations of State for the volume and the unit-cell parameters for stiff materials, such as rutile. In combination with published data for garnets, the Equation of State for rutile indicates that rutile inclusions trapped inside garnets in metamorphic rocks should exhibit negative residual pressures when measured at room conditions.

Keywords

rutilehigh pressurehigh temperatureelasticityP–V–T–K fitEosFitnegative residual pressures
Type
Article
Information
Mineralogical Magazine , Volume 83 , Issue 3 , June 2019 , pp. 339 - 347
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019 

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Footnotes

Associate Editor: Andrew G Christy

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