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Surface Enhanced Raman Scattering (SERS) Effects of 4-Aminothiophenol on Au Nanoparticles with Different Shapes

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Au nanoparticles with different shapes (nanosphere, nanoplate and nanorod) have been synthesized and were characterized by scanning electron microscope, transmission electron microscopy, X-ray diffraction and UV-vis absorption spectroscopy. We investigated the catalytic activity of Au nanoparticles with different morphologies as surface-enhanced Raman scattering substrates for the conversion of p-aminothiophenol to p,p′-dimercaptoazobenzene. The experimental results indicated that the order of catalytic activity is nanorod> nanoplate> nanosphere under 633 and 785 nm excitation. The current research provides some reliable insights and important references for exploration new catalysts and their catalytic activities from the perspectives of different sizes, morphology and crystal composition of nanomaterials.

Keywords: 4-Aminothiophenol; Au Nanoparticle; Photocatalysis; SERS

Document Type: Research Article

Affiliations: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi’an 710127, People’s Republic of China

Publication date: 01 September 2020

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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