Solution-Processable Diketopyrrolopyrrole Derivatives as Organic Semiconductors for Organic Thin-Film Transistors
Solution-processable diketopyrrolopyrrole derivatives having acetylene, 2,5-bis(2-ethylhexyl)-3-(5-(phenylethynyl)thiophen-2-yl)-6-(thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione (3), 2,5-bis (2-ethylhexyl)-3-(thiophen-2-yl)-6-(5-(thiophen-2-ylethynyl)thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]
pyrrole-1,4-dione (4), and 6,6′-((thiophene-2,5-diylbis(ethyne-2,1-diyl))bis(thiophene-5,2-diyl)) bis(2,5-bis(2-ethylhexyl)-3-(thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione) (5) were synthesized and characterized as organic semiconductors for organic
thin-film transistors (OTFTs). For the fabrication of thin films based on solution processable compounds, drop-casting (DC) and solution-shearing (SS) were employed. Thin films of compound 5 exhibited p-channel characteristics with carrier mobility as high as 5.7 × 10−4
cm2/Vs and a current on/off ratio of 104–106 for top-contact/bottom-gate OTFT devices.
Keywords: Acetylene; Diketopyrrolopyrrole; Organic Thin-Film Transistors; Self-Assembled Monolayer; Semiconductor
Document Type: Research Article
Affiliations: 1: Department of Chemical and Biomolecular Engineering, Sogang University, Seoul 04107, Korea 2: Department of Chemistry, Pukyong National University, Busan 48513, Korea
Publication date: 01 January 2018
- Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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