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Enhanced H2 and Reduced CO Level by Use of Electrospun CuO/CeO2 Nanofibers Catalyst for Water Gas Shift Reaction

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The CuO/CeO2 nanofibers were prepared by electrospinning of raw material, precursor Ce(NO3)3 · 6H2O and spinnable additive polyvinyl pyrrolidone (PVP). The diameter of nanofibers ranged between 40 to 100 nm depending upon PVP concentration. In comparison to pure CeO2 nanofibers, equistoichiometric ratio of cerium nitrate and copper acetate monohydrate mixed solution resulted in thinner fibers and superior catalytic activity in water gas shift reaction (WGSR). In this case CO conversion improved by 7% and reached to 72% in temperatures range 310 °C to 360 °C, signifying its potential application in water gas shift reaction.

Keywords: Cerium Oxide; Electrospinning; Nanofibers; WGSR

Document Type: Research Article

Affiliations: 1: Department of Chemical Engineering and Technology, Indian Institute of Technology, B. H. U., Varanasi 221005, U.P., India 2: Defense Research and Development Organization (DRDO), Jagdalpur, Chhattisgarh, India 3: Department of Chemistry, Indian Institute of Technology, B. H. U., Varanasi 221005, U.P., India

Publication date: 01 April 2016

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