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Radiation chemical investigations on aqueous solutions of C60(OH)18

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Abstract

The ultraviolet-visible absorption spectrum of C60(OH)18 in water showed an absorption band with λmax = 215 nm and other characteristic absorption bands of C60 are not observed. The singlet-singlet and triplet-triplet absorption bands are not observed in the 400–900 nm region. It has low reactivity with e −aq and formed an absorption band with λmax = 580 nm. The hydroxyl radicals react with a bimolecular rate constant of 2.4×109 dm3 mol−1 s−1 and showed an absorption band at 540 nm.

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Author notes

  1. J. P. Mittal

    Present address: Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore, India

Authors and Affiliations

  1. Chemistry Division, Bhabha Atomic Research Centre, 400 085, Bombay, India

    H. Mohan & J. P. Mittal

  2. Centre for Condensed Matter Science, National Taiwan University, 10764, Taipei, Taiwan

    L. Y. Chiang

Authors
  1. H. Mohan
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  2. L. Y. Chiang
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  3. J. P. Mittal
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Mohan, H., Chiang, L.Y. & Mittal, J.P. Radiation chemical investigations on aqueous solutions of C60(OH)18 . Res. Chem. Intermed. 23, 403–414 (1997). https://doi.org/10.1163/156856797X00150

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  • DOI: https://doi.org/10.1163/156856797X00150

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