Zinc‐Substituted α‐Nickel Hydroxide as an Electrode Material for Alkaline Secondary Cells

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© 1999 ECS - The Electrochemical Society
, , Citation Mridula Dixit et al 1999 J. Electrochem. Soc. 146 79 DOI 10.1149/1.1391567

1945-7111/146/1/79

Abstract

Double hydroxides of the formula, having the same structure as that of α‐nickel hydroxide have been synthesized by partial substitution of zinc for nickel. The hydroxide having the composition x = 0.25 exhibits prolonged stability in 6 M KOH. Pasted electrodes comprising this material are rechargeable with a stabilized reversible discharge capacity of of nickel even under suboptimal conditions of electrode fabrication. This compares favorably with the capacity values achieved for β‐nickel hydroxide (, This work; , Delahaye‐Vidal and Figlarz; , theoretical). © 1999 The Electrochemical Society. All rights reserved.

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10.1149/1.1391567