Abstract.
Silver (Ag) and silver sulfide (Ag2S) nanoparticles were synthesized in a sago starch matrix. The resulting nanocomposites were investigated using structural, optical and thermal methods. XRD spectra of the nanocomposites confirmed the presence of nanostructured silver (cubic phase) and silver sulfide (monoclinic phase) in the matrix. TEM micrographs showed that the nanoparticles are mostly spherical in shape. Analyzes of the optical properties of the silver nanocomposite aqueous dispersions/solutions of various concentrations were carried out. The results and the theoretical considerations suggested that at high concentrations there is a release of silver nanoparticles from the composite in the water environment. Further dilution produces homogeneous solution in which silver nanoparticles are capped with starch macromolecules. TGA analysis revealed reduced thermal stability of the nanocomposites with respect to pure starch matrix.
Similar content being viewed by others
References
H. Haizhen, Y. Qiang, Y. Xiurong, Coll. Surf. B: Biointerfaces 39, 31 (2004)
T. Miyama, Y. Yonezawa, J. Nanopar. Res. 6, 457 (2004)
Y. Yonezawa, N. Kometani, M. Seki, T. Sakagami, H. Tanaka, S. Koyanagi, T. Miyama, Trans. Mater. Res. Soc. Jpn 27, 197 (2002)
Z.H. Mbhele, M.G. Salemane, C.G.C.E. van Sittert, J.M. Nedeljković, V. Djoković, A.S. Luyt, Chem. Mater. 15, 5019 (2003)
J.-F. Zhu, Y.-J. Zhu, J. Phys. Chem. B 110, 8593 (2006)
S. Manna, S.K. Batabyal, A.K. Nandi, J. Phys. Chem. B 110, 12318 (2006)
P.V. Adhyapak, P.K. Khanna, J.W. Dadge, R.C. Aiyer, J. Nanosci. Nanotechnol. 6, 2141 (2006)
K. Akamatsu, S. Takei, M. Mizuhata, A. Kajinami, S. Deki, S. Takeoka, M. Fujii, S. Hayashi, K. Yamamoto, Thin Solid Films 55, 359 (2000)
Y. Dirix, C. Bastiaansen, W. Caseri, P.J. Smith, Mater. Sci. 34, 3859 (1999)
T.C. Wang, M.F. Rubner, R.E. Cohen, Langmuir 18, 3370 (2002)
K. Esumi, R. Isono, T. Yoshimura, Langmuir 20, 237 (2004)
H. Haizhen, Y. Qiang, Y. Xiurong, J. Coll. Interf. Sci. 282, 26 (2005)
K. Malick, M.J. Witcomb, M.S. Scurrell, Eur. Phys. J. E 19, 149 (2006)
K. Malick, M.J. Witcomb, M.S. Scurrell, Eur. Phys. J. E 20, 347 (2006)
M. Iwamoto, K. Kuroda, V. Zaporojtchenko, S. Hayashi, F. Faupel, Eur. Phys. J. D 24, 365 (2003)
Y. Zhu, Y. Qian, X. Li, M. Zhang, Nanostruct. Mater. 10, 673 (1998)
Z. Zhang, M.J. Han, Mater. Chem. Commun. 13, 641 (2003)
T. Ung, L.M. Liz-Marzán, P. Mulvaney, J. Phys. Chem. B 105, 3441 (2001)
I. Hussain, M. Brust, A.J. Papworth, A.I. Cooper, Langmuir 19, 4831 (2003)
D.H. Cole, K.R. Shull, P. Baldo, L. Rehn, Macromolecules 32, 771 (1999)
W. Caseri, Macromol. Rapid Commun. 21, 705 (2000)
D.Y. Godovsky, Advan. Polym. Sci. 153, 163 (2000)
X. Lu, L. Li, W. Zhang, C. Wang, Nanotechnology 16, 2233 (2005)
X.F. Qian, J. Yin, S. Feng, S.H. Liu, Z.K. Zhu, J. Mater. Chem. 11, 2504 (2001)
X.F. Qian, J. Yin, J.C. Huang, Y.F. Yang, X.X. Guo, Z.K. Zhu, Mater. Chem. Phys. 68, 95 (2001)
T.G. Schaaff, A.J. Rodinone, J. Phys. Chem. B 107, 10416 (2003)
S.H. Yu, M. Yoshimura, J.M.C. Moreno, T. Fujiwara, T. Fujino, R. Teranishi, Langmuir 17, 1700 (2001)
M. Tamborra, M. Striccoli, R. Comparelli, M.L. Curri, A. Petrella, A. Agostiano, Nanotechnology 15, 240 (2004)
H. Du, G.Q. Xu, W.S. Chin, L. Huang, W. Ji, Chem. Mater. 14, 4473 (2002)
D. Šajinović, Z.V. Šaponjić, N. Cvjetičanin, M. Marinović-Cincović, J.M. Nedeljković, Chem. Phys. Lett. 329, 168 (2000)
P.S. Nair, T. Radhakrishnan, N. Revaprasadu, G.A. Kolawole, A.S. Luyt, V. Djoković, J. Phys. Chem. Solid. 66, 1302 (2005)
P.S. Nair, T. Radhakrishnan, N. Revaprasadu, G.A. Kolawole, A.S. Luyt, V. Djoković, Appl. Phys. A Mater. Sci. Proces. 81, 835 (2005)
V. Djoković, J.M. Nedeljković, Macromol. Rapid. Commun. 21, 994 (2000)
Y. Wang, N. Herron, J. Phys. Chem. 95, 525 (1991)
K. Sattler, Handbook of Thin Films Materials, edited by H.S. Nalwa (Academic Press, 2002), Vol. 5, p. 61
P. Raveendran, J. Fu, S.L. Wallen, J. Am. Chem. Soc. 125, 13940 (2003)
P. Podsiadlo, S. Paternel, J.-M. Rouillard, Z. Zhang, J. Lee, J.-W. Lee, E. Gulari, N.A. Kotov, Langmuir 21, 11915 (2005)
P. Raveendran, J. Fu, S.L. Wallen, Green Chem. 8, 34 (2006)
T.K. Sarma, A. Chattopadhyay, Langmuir 20, 3520 (2004)
Q. Wei, S.-Z. Kang, J. Mu, Colloid Surf. A: Physicochem. Eng. Aspects 247, 125 (2004)
M.C. Brelle, J.Z. Zhang, L. Nguyen, R.K. Mehra, J. Phys. Chem. A 103, 10194 (1999)
J. Apreadborough, J.W. Christian, J. Sci. Instr. 36, 116 (1959)
R. Sadanga, S. Sueno, Mineral. J. 5, 124 (1967)
C.F. Bohren, D.R. Huffman, Absorption and Scattering of Light by Small Particles (Wiley, New York, 1983)
P.B. Johnson, R.W. Christy, Phys. Rev. B 6, 4370 (1972)
H. Hövel, S. Fritz, A. Hilger, U. Kreibig, M. Vollmer, Phys. Rev. B 48, 18178 (1993)
A.C. Templeton, J.J. Pietron, R.W. Murray, P. Mulvaney, J. Phys. Chem. B 104, 564 (2000)
P. Mulvaney, Langmuir 12, 788 (1996)
K. Chatterjee, S. Banerjee, D. Chakravorty, Phys. Rev. B 66, 085421 (2002)
Z.V. Šaponjić, R. Csencsits, T. Rajh, N.M. Dimitrijević, Chem. Mater. 15, 4521 (2003)
C. Oubre, P. Nordlander, J. Phys. Chem. B 109, 10042 (2005)
R. Babu, J. Zhang, E.J. Beckman, M. Virji, W.A. Pasculle, A. Wells, Biomaterials 27, 4304 (2006)
D. French, Starch: Chemistry and Technology, 2nd edn., edited by R.L. Whistler, J.N. Bemiller, E.F. Paschall (Academic Press, Orlando, Fla. 1984)
X.Q. Zhang, J. Golding, I. Burgar, Polymer 43, 5791 (2002)
H.-M. Park, W.-K. Lee, C.-Y. Park, W.-J. Cho, C.-S. Ha, J. Mater. Sci. 38, 909 (2003)
J.K. Pandey, R.P. Singh, Starch/Stärke 57, 8 (2005)
M.-F. Huang, J.-G. Yu, X.-F. Ma, Polymer 45, 7017 (2004)
M.-F. Huang, J.-G. Yu, X.-F. Ma, P. Jin, Polymer 46, 3157 (2005)
H.H. Horowitz, G. Metzger, Anal. Chem. 35, 1465 (1963)
A. Broido, J. Polym. Sci. 7, 1761 (1969)
J.F. Mano, D. Koniarova, R.L. Reis, J. Mater. Sci. Mater. Med. 14, 127 (2003)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Božanić, D., Djoković, V., Blanuša, J. et al. Preparation and properties of nano-sized Ag and Ag2S particles in biopolymer matrix. Eur. Phys. J. E 22, 51–59 (2007). https://doi.org/10.1140/epje/e2007-00008-y
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1140/epje/e2007-00008-y