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Structure of the first nitrosoammine complexes of ruthenium with a coordinated sulfate ion: [Ru(NO)(NH3)4(SO4)](HSO4)·H2O and [Ru(NO)(NH3)3Cl(SO4)]·2H2O

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Abstract

We present a thermogravimetric study of the thermolysis of trans-[Ru(NO)(NH3)4(H2O)](HSO4)SO4 in a helium atmosphere. The intermediate product of thermolysis (at 186°C) is treated with a 2 M H2SO4 solution to obtain the first example of a sulfate ammine complex of nitrosoruthenium [Ru(NO)(NH3)4(SO4)](HSO4)·H2O (I) with a ∼70% yield. The product of higher temperature thermolysis (220°C) is treated with acids (H2SO4 and HCl) to obtain a triammine complex [Ru(NO)(NH3)3Cl(SO4)]·2H2O (II). The structure of the compounds is found by single crystal XRD: Pna21 space group, a = 10.8005(2) Å, b = 14.9032(3) Å, c = 7.7603(1) Å) (I) and P21/n space group, a = 8.9397(1) Å, b = 8.3276(1) Å, c = 13.8993(2) Å; β = 97.358(1)° (II).

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    A. N. Makhinya, E. A. Shusharina, I. A. Baidina & M. A. Il’in

  2. Novosibirsk State University, Novosibirsk, Russia

    A. N. Makhinya, E. A. Shusharina & M. A. Il’in

Authors
  1. A. N. Makhinya
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  2. E. A. Shusharina
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  3. I. A. Baidina
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  4. M. A. Il’in
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Correspondence to A. N. Makhinya.

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Original Russian Text Copyright © 2011 by A. N. Makhinya, E. A. Shusharina, I. A. Baidina, and M. A. Il’in

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Translated from Zhurnal Strukturnoi Khimii, Vol. 52, No. 5, pp. 973–980, September–October, 2011.

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Makhinya, A.N., Shusharina, E.A., Baidina, I.A. et al. Structure of the first nitrosoammine complexes of ruthenium with a coordinated sulfate ion: [Ru(NO)(NH3)4(SO4)](HSO4)·H2O and [Ru(NO)(NH3)3Cl(SO4)]·2H2O. J Struct Chem 52, 946–953 (2011). https://doi.org/10.1134/S0022476611050167

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  • DOI: https://doi.org/10.1134/S0022476611050167

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