Skip to main content
SpringerLink
Log in

Sibunit-based catalytic materials for the deep oxidation of organic ecotoxicants in aqueous solutions. III: Wet air oxidation of phenol over oxidized carbon and Rr/C catalysts

  • Domestic Catalysts
  • Published:
Catalysis in Industry Aims and scope Submit manuscript

Abstract

This article presents the first systematic study concerning the effect of the oxidative treatment conditions on the surface chemical composition and the catalytic properties in the deep wet oxidation of organic ecotoxicants of a Sibunit type carbon material (S4) which was earlier identified as promising for the oxidative treatment of industrial wastewaters. The influence of the surface chemistry of the carbon materials oxidized under different conditions on the catalytic performances in the wet air oxidation of phenol of the bare carbon materials as well as the ruthenium-containing catalysts (3 wt % Ru) supported on the oxidized carbon samples was studied. The catalytic activity of the bare carbon samples appeared to be moderate and either (i) increased with the total number of carbonyl and phenolic surface groups or (ii) decreased with the total concentration of surface carboxylic and lactonic species. However, the catalytic performances of the Ru-containing catalysts were significantly higher. Based on our results, an optimum pretreatment of the carbon support could be identified to obtain the most stable and active Sibunit-supported ruthenium catalysts in the wet air oxidation of phenols.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Luck, F., Catal. Today, 1996, vol. 27, nos. 1–2, p. 195.

    Article  CAS  Google Scholar 

  2. Luck, F., Catal. Today, 1999, vol. 53, no. 1, p. 81.

    Article  CAS  Google Scholar 

  3. Mishra, V.S., Mahajani, V.V., and Joshi, J.B., Ind. Eng. Chem. Res., 1995, vol. 34, no. 1, p. 2.

    Article  CAS  Google Scholar 

  4. Stüber, F., Font, J., Fortuny, A., Bengoa, C., Eftaxias, A., and Fabregat, A., Top. Catal., 2005, vol. 33, no. 1, p. 3.

    Article  Google Scholar 

  5. Bhargava, S.K., Tardio, J., Prasad, J., Föger, K., Akolekar, D., and Grocott, S., Ind. Eng. Chem. Res., 2006, vol. 45, no. 4, p. 1221.

    Article  CAS  Google Scholar 

  6. Kim, K.-H. and Ihm, S.-K., J. Hazard. Mater., 2011, vol. 186, no. 1, p.16.

    Article  CAS  Google Scholar 

  7. Jing, G., Luan, M., and Chen, T., Arab. J. Chem., doi:10.1016/j.arabjc.2012.01.001.

  8. Gallezot, P., Chaumet, S., Perrard, A., and Isnard, P., J. Catal., 1997, vol. 168, no. 1, p. 104.

    Article  CAS  Google Scholar 

  9. Ukropec, R., Kuster, B.F.M., Schouten, J.C., and van Santen, R.A., Appl. Catal. B, 1999, vol. 23, no. 1, p. 45.

    Article  CAS  Google Scholar 

  10. Torre, T., Aricò, A.S., Alderucci, V., Antonucci, V., and Giordano, N., Appl. Catal. A, 1994, vol. 114, no. 2, p. 257.

    Article  CAS  Google Scholar 

  11. Ovejero, G., Sotelo, J.L., Romero, M.D., Rodríguez, A., Ocaña, M. A., Rodríguez, G., and García, J., Ind. Eng. Chem. Res., 2006, vol. 45, no. 7, p. 2206.

    Article  CAS  Google Scholar 

  12. Tang, T., Yin, Ch., Xiao, N., Guo, M., and Xiao, F.-S., Catal. Lett., 2009, vol. 127, nos. 3–4, p. 400.

    Article  CAS  Google Scholar 

  13. Quintanilla, A., Casas, J.A., and Rodriguez, J.J., Appl. Catal. B, 2007, vol. 76, nos. 1–2, p. 135.

    CAS  Google Scholar 

  14. Dobrynkin, N.M., Batygina, M.V., Noskov, A.S., Tsyrulnikov, P.G., Shlyapin, D.A., Schegolev, V.V., Astrova, D.A., and Laskin, B.M., Top. Catal., 2005, vol. 33, nos. 1–4, p. 69.

    Article  CAS  Google Scholar 

  15. Fortuny, A., Font, J., and Fabregat, A., Appl. Catal. B, 1998, vol. 19, nos. 3–4, p. 165.

    CAS  Google Scholar 

  16. Santiago, M., Stüber, F., Fortuny, A., Fabregat, A., and Font, J., Carbon, 2005, vol. 43, no. 10, p. 2134.

    Article  CAS  Google Scholar 

  17. Santos, A., Yustos, P., Cordero, T., Gomis, S., Rodríguez, S., and García-Ochoa, F., Catal. Today, 2005, vol. 102–103, p. 213.

    Article  Google Scholar 

  18. Santos, A., Yustos, P., Rodriquez, S., Garcia-Ochoa, F., and de Gracia, M., Ind. Eng. Chem. Res., 2007, vol. 46, no. 8, p. 2423.

    Article  CAS  Google Scholar 

  19. Taran, O., Polyanskaya, E., Ogorodnikova, O., Kuznetsov, V., Parmon, V., Besson, M., and Descorme, C., Appl. Catal. A, 2010, vol. 387, nos. 1–2, p. 55.

    CAS  Google Scholar 

  20. Taran, O., Polyanskaya, E., Ogorodnikova, O., Descorme, C., Besson, M., and Parmon, V., Catal. Ind., 2011, vol. 3, no. 2, p. 161.

    Article  Google Scholar 

  21. Taran, O., Polyanskaya, E., Ogorodnikova, O., Descorme, C., Besson, M., and Parmon, V., Catal. Ind., 2010, vol. 2, no. 4, p. 381.

    Article  Google Scholar 

  22. Pham Minh, D., Aubert, G., Gallezot, P., and Besson, M., Appl. Catal. B, 2007, vol.73, nos. 3–4, p. 236.

    Google Scholar 

  23. Anderson, J.R., Structure of Metallic Catalysts, London-New York: Academic Press Inc, 1975.

    Google Scholar 

  24. Parmon, V.N., Dokl. Phys. Chem., 2007, vol. 42, p. 413.

    Google Scholar 

  25. Gallezot, P., Laurain, N., and Isnard, P., Appl. Catal. B, 1996, vol. 9, nos. 1–4, p. L11.

    CAS  Google Scholar 

  26. Gallezot, P., Chaumet, S., Perrard, A., and Isnard, P., J. Catal., 1997, vol. 168, no. 1, p. 104.

    Article  CAS  Google Scholar 

  27. Beck, I.E., Bukhtuyarov, V.I., Pakharukov, I.Yu., Zaikovsky, V.I., Kriventsov, V.V., and Parmon, V.N., J. Catal., 2009, vol. 268, no. 1, p. 60.

    Article  CAS  Google Scholar 

  28. Hicks, R.F., Qi, H., Young, M.L., and Lee, R.G., J. Catal., 1990, vol. 122, no. 2, p. 280.

    Article  CAS  Google Scholar 

  29. Otto, K., Langmuir, 1989, vol. 5, no. 6, p. 1364.

    Article  CAS  Google Scholar 

  30. Delidovich, I.V., Moroz, B.L., Taran, O.P., Gromov, N.V., Pyrjaev, P.A., Prosvirin, I.P., Bukhtiyarov, V.I., and Parmon, V.N., Chem. Eng. J., 2013, vol. 223, p. 921.

    Article  CAS  Google Scholar 

  31. Oliviero, L., Barbier, J., Duprez, D., Guerrero-Ruiz, A., Bachiller-Baeza, B., and Rodrguez-Ramos, I., Appl. Catal. B, 2000, vol. 25, no. 4, p. 267.

    Article  CAS  Google Scholar 

  32. Castillejos-López, E., Maroto-Valiente, A., Nevskaia, D., Muñoz, V., Rodríguez-Ramos., I., and Guerrero-Ruiz., A., Catal. Today, 2009, vol. 143, nos. 3–4, p. 355.

    Article  Google Scholar 

  33. Keav, S., Martin, A., Barbier, J., and Duprez, D., Catal. Today, 2010, vol. 151, nos. 1–2, p. 143.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090, Russia

    O. P. Taran, E. M. Polyanskaya, A. B. Ayusheev & V. N. Parmon

  2. Novosibirsk State Technical University, Novosibirsk, 630073, Russia

    O. P. Taran

  3. Institut de recherches sur la catalyse et l’environnement de Lyon, CNRS-Université de Lyon, Villeurbanne, 69626, France

    C. Descorme, E. M. Polyanskaya & M. Besson

  4. Novosibirsk State University, Novosibirsk, 630090, Russia

    V. N. Parmon

Authors
  1. O. P. Taran
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. Descorme
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. M. Polyanskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. B. Ayusheev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. Besson
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. N. Parmon
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © O.P. Taran, C. Descorme, E.M. Polyanskaya, A.B. Ayusheev, M. Besson, V.N. Parmon, 2013, published in Kataliz v Promyshlennosti.

The article was translated by the authors.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Taran, O.P., Descorme, C., Polyanskaya, E.M. et al. Sibunit-based catalytic materials for the deep oxidation of organic ecotoxicants in aqueous solutions. III: Wet air oxidation of phenol over oxidized carbon and Rr/C catalysts. Catal. Ind. 5, 164–174 (2013). https://doi.org/10.1134/S2070050413020104

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070050413020104

Keywords

Search

Navigation