References
Simagina, V.I., Milova, L.P., and Parmon, V.N., Metals in Commercial Catalysts: 1. Molybdenum and Tungsten, Catal. Ind., 2009, no. 4, p. 6.
Széchenyi, A. and Solymosi, F., n-Octane Aromatization on Mo2C-Containing Catalysts, Appl. Catal., A, 2006, vol. 306, no. 1, p. 149.
Maméde, A.S., Giraudon, J.-M., Löfberg, A., Leclercq, L., and Leclercq, G., Hydrogenation of Toluene over β-Mo2C in the Presence of Thiophene, Appl. Catal., A, 2002, vol. 227, nos. 1–2, p. 73.
Solymosi, F. and Szoke, A., Conversion of Ethane into Benzene on Mo2C/ZSM-5 Catalyst, Appl. Catal., A, 1998, vol. 166, no. 1, p. 225.
Xiang, M., Zou, J., Li, D., Li, W., Sun, Y., and She, X., Nickel and Potassium Co-Modified β-Mo2C Catalyst for CO Conversion, J. Nat. Gas Chem., 2009, vol. 18, no. 2, p. 183.
Solymosi, F., Németh, R., and Oszkó, A., The Oxidative Dehydrogenation of Propane with CO2 Over Supported Mo2C Catalyst, Stud. Surf. Sci. Catal., 2001, vol. 136, p. 339.
Ardakani, S.J., Liu, X., and Smith, K.J., Hydrogenation and Ring Opening of Naphthalene on Bulk and Supported Mo2C Catalysts, Appl. Catal., A, 2007, vol. 324, no. 1, p. 9.
Lin, S.S.-Y., Thomson, W.J., Hagensen, T.J., and Ha, S.Y., Steam Reforming of Methanol Using Supported Mo2C Catalysts, Appl. Catal., A, 2007, vol. 318, p. 121.
Marin Flores, O.G. and Ha, S., Study of the Performance of Mo2C for iso-Octane Steam Reforming, Catal. Today, 2008, vol. 136, nos. 3–4, p. 235.
Wang, J., Ji, Sh., Yang, J., Zhu, Q., and Li, S., Mo2C and Mo2C/Al2O3 Catalysts for NO Direct Decomposition, Catal. Commun., 2005, vol. 6, no. 6, p. 389.
Oxley, J.D., Mdleleni, M.M., and Suslick, K.S., Hydrodehalogenation with Sonochemically Prepared Mo2C and W2C, Catal. Today, 2004, vol. 88, nos. 3–4, p. 139.
Patt, J., Moon, D.J., Phillips, C., and Thompson, L., Molybdenum Carbide Catalyst for Water-Gas Shift, Catal. Lett., 2000, vol. 65, p. 193.
Moon, D.J. and Rue, J.W., Molybdenum Carbide Water-Gas Shift Catalyst for Fuel Cell-Powered Vehicles Application, Catal. Lett., 2004, vol. 92, no. 1, p. 17.
Oyama, S.T., Preparation and Catalytic Properties of Transition Metal Carbides and Nitrides, Catal. Today, 1992, vol. 15, no. 2, p. 179.
York, A.P.E., Clarige, J.B., Marquez-Alvarez, C., Brungs, A.J., Tsang, S.C., and Green, M.L.H., Synthesis of Early Transition Metal Carbides and Their Application for the Reforming of Methane to Synthesis Gas, Stud. Surf. Sci. Catal., 1997, vol. 110, p. 711.
Clarige, J.B., York, A.P.E., Brungs, A.J., Marquez-Alvares, C., Sloan, J., Tsang, S.C., and Green, M.L.H., New Catalysts for Conversion of Methane to Synthesis Gas: Molybdenum and Tungsten Carbide, J. Catal., 1998, vol. 180, no. 1, p. 85.
Faul, W. and Kastening, B., US Patent 4159309, 1979.
Vreugdenhil, W., Sherif, F.G., Burk, J.H., and Gadberry, J.F., US Patent 5311161, 1993.
Jacquot, R. and Mercier, C., US Patent 5646085, 1997.
Becnel, B.F., Sabahi, M., and Theriot, K.J., US Patent 5907069, 1999.
Sabahi, M., Teriot, K.J., and Becnel, B., WO Patent 9830528, 1998.
Sherif, F.G., US Patent 5426252, 1995.
Pavlov, D., Donchev, T.V., Nikolov, I.P., Nikolova, V.I., Papazov, G.P., and Petrov, K.M., US Patent 4925746, 1990.
Baresel, D., Gellert, W., and Scharner, P., US Patent 3902917, 1975.
Finch, J.N., US Patent 4219445, 1980.
Finch, J.N., US Patent 4155928, 1979.
Slaugh, L.H. and Hoxmeier, R.J., US Patent 4326992, 1982.
Sherif, F.G. and Vreugdenhil, W., US Patent 5330944, 1994.
Sherif, F.G., US Patent 0 569 084, 1993.
Wu, A. and Drake, C.A., US Patent 5776852, 1998.
Sherif, F.G., US Patent 5384027, 1995.
Tonkovich, A., Vang I., and Vanderveil, D.P., RF Patent 2003126180, 2005.
Drake, C.A. and Wu, A., US Patent 5965782, 1999.
Gaffney, A.M., WO Patent 2001/0 128 679, 2001.
Gaffney, A.M., WO Patent 2002/2 002 198 101, 2002.
Seegopaul, P. and Gao, L., WO Patent 2002/02 076 885, 2004.
Thompson, L., Patt, J., Moon, D.J., and Phillips, C., US Patent 6 623 720, 2003.
Slaugh, L.H. and Hoxmeier, R.J., US Patent 4325842, 1982.
Lee, J.S., Oyama, S.T., and Boudart, M., Molybdenum Carbide Catalysts: I. Synthesis of Unsupported Powders, J. Catal., 1987, vol. 106, p. 125.
Li, S., Lee, J.S., Hyeon, T., and Suslick, K.S., Catalytic Hydrodenitrogenation of Indole over Molybdenum Nitride and Carbides with Different Structures, Appl. Catal., A, 1999, vol. 184, p. 1.
Kojima, R. and Aika, K., Molybdenum Nitride and Carbide Catalysts for Ammonia Synthesis, Appl. Catal., A, 2001, vol. 219, p. 141.
Moon, D.J. and Woo, R.J., Molybdenum Carbide Water-Gas Shift Catalyst for Fuel Cell-Powered Vehicles Applications, Catal. Lett., 2004, vol. 92, p. 1.
Moon, D.J., Screekumar, K., Lee, S.D., Lee, B.G., and Kim, H.S., Studies on Gasoline Fuel Processor System for Fuel-Cell Powered Vehicles Application, Appl. Catal., A, 2001, vol. 215, p. 1.
Patt, J., Moon, D.J., Phillips, C., and Thomson, L., Molybdenum Carbide Catalysts for Water-Gas Shift, Catal. Lett., 2000, vol. 65, p. 193.
Oyama, S.T., Charles, Y.C., and Ramanathan, S., Transition Metal Bimetallic Oxycarbides: Synthesis, Characterization, and Activity Studies, J. Catal., 1999, vol. 184, p. 535.
Volpe, L. and Boudart, M., Compounds of Molybdenum and Tungsten with High Specific Surface Area, J. Solid State Chem., 1985, vol. 59, p. 348.
Manoli, J.-M., Da Costa, P., Brun, M., Vrinat, M., Maugé, F., and Potvin, C., Hydrodesulfurization of 4,6-Dimethyldibenzothiophene over Promoted (Ni, P) Alumina-Supported Molybdenum Carbide Catalysts: Activity and Characterization of Active Sites, J. Catal., 2004, vol. 221, p. 365.
Wang, X.H., Hao, H.L., Zhang, M.H., Li, W., and Tao, K.Y., Synthesis and Characterization of Molybdenum Carbides Using Propane as Carbon Source, J. Solid State Chem., 2006, vol. 179, p. 538.
Slaugh, L.H. and Hoxmeier, R.J., US Patent 4325843, 1982.
Boudart, M. and Oyama, S., US Patent 4 851 206, 1989.
Hyeon, T., Fang, M., and Suslick, K.S., Nanostructured Molybdenum Carbide: Sonochemical Synthesis and Catalytic Properties, J. Am. Chem. Soc., 1996, vol. 118, p. 5492.
Roman, P., Luque, A., and Aranzabe, A., Synthesis of Oxides, Oxocarbides and Carbides of Molybdenum by Thermal Decomposition of Diethylenetriamine Oxomolybdenum Compounds, Thermochim. Acta, 1993, vol. 223, p. 167.
Gu, Y., Li, Z., Chen, L., Ying, Y., and Qian, Y., Synthesis of Nanocrystalline Mo2C via Sodium Co-Reduction of MoCl5 and CBr4 in Benzene, Mater. Res. Bull., 2003, vol. 38, p. 1119.
Lu, J., Hugosson, H., Eriksson, O., Nordstrom, L., and Jansson, U., Chemical Vapour Deposition of Molybdenum Carbides: Aspects of Phase Stability, Thin Solid Films, 2000, vol. 370, p. 203.
Monteverdi, S., Mercy, M., Molina, S., Bettahar, M.M., Puricelli, S., Be’gin, D., Maréché, F., and Furdin, F., Study of Unsupported and Active Carbon Supported β-Mo2C Prepared from MoCl5 Precursor, Appl. Catal., A, 2002, vol. 230, p. 99.
Weigert, E.C., South, J., Rykov, S.A., and Chen, J.G., Multifunctional Composites Containing Molybdenum Carbides as Potential Electrocatalysts, Catal. Today, 2005, vol. 99, p. 285.
Shapoval, V.I., Malyshev, V.V., Novoselova, I.N., and Kushkhov, Kh.B., Current Problems of the Electrochemical Synthesis of Group IV-VI Transition Metal Compounds, Usp. Khim., 1995, vol. 64, no. 2, p. 133.
Gurin, V.N., Synthesis Methods for Refractory Compounds of Transition Metals and Their Development Prospects, Usp. Khim., 1972, vol. 41, p. 616.
Hoschowa, K., J. Jpn. Soc. Heat Treat., 1980, vol. 20, p. 130.
Arai, T., Sugimoto, Y., and Komatsu, N., Carbide Coating and Boriding of Chromium-Plated Steel by Immersion Process in Fused Borax Bath, J. Met. Finish. Soc. Jpn., 1981, vol. 32, p. 240.
Andrieux, J.L. and Weiss, G., Making Compounds of Molybdenum and of Tungsten by Electrolysis of Melts, Bull. Soc. Chim. Fr., 1948, vol. 15, p. 598.
Gomes, J. M., Baker, D.H., and Uchida, K., US Patent 3 589 987, 1971.
Suri, A.K., Musherjee, T.K., and Cupta, C.K., Molybdenum Carbide by Electrolysis of Sodium Molybdate, J. Electrochem. Soc., 1973, vol. 120, no. 5, p. 622.
Barlett, H.E. and Johnson, K.E., Electrochemical Studies in Molten Li2CO3-Na2CO3, J. Electrochem. Soc., 1967, vol. 114, no. 5, p. 457.
Delimarskii, Yu.K., Grishchenko, V.F., and Gorodyskii, A.V., A Study of the Reactions Occurring during the Electrolysis of Molten Carbonates, Ukr. Khim. Zh., 1965, vol. 31, no. 1, p. 32.
Rebrov, E.V., Kuznetsov, S.A., de Croon, M.H.J.M., and Schouten, J.C., Study of the Water-Gas Shift Reaction on Mo2C/Mo Catalytic Coatings for Application in Microstructured Fuel Processors, Catal. Today, 2007, vol. 125, nos. 1–2, p. 88.
Kuznetsov, S.A., Dubrovskiy, A.R., Rebrov, E.V., and Schouten, J.C., Electrochemical Synthesis of Mo2C Catalytical Coatings for the Water-Gas Shift Reaction, Z. Naturforsch., A: Phys. Sci., 2007, vol. 62, nos. 10–11, p. 647.
Dubrovskii, A.R., Kuznetsov, S.A., Rebrov, E.V., and Schouten, J.C., Catalytic Mo2C Coatings for the Water Gas Shift Reaction: Electrosynthesis in Molten Salts, Kinet. Catal., 2008, vol. 49, no. 4, p. 594.
Dubrovskii, A.R., Kuznetsov, S.A., Rebrov, E.V., Schouten, J.C., and Kalinnikov, V.T., Synthesis of Mo2C Coatings by Simultaneous Electroreduction of and Ions in Molten Salts and Their Catalytic Activity for the Water-Gas Shift Reaction, Dokl. Chem., 2008, vol. 421,part 2, p. 186.
Dubrovskiy, A.R., Rebrov, E.V., Kuznetsov, S.A., and Schouten, J.C., A Microstructured Reactor/Heat-Exchanger for the Water-Gas Shift Reaction Operated in the 533–673 K Range, Catal. Today, 2009, vol. 147,suppl. 1, p. 198.
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Original Russian Text © G.L. Semin, A.R. Dubrovskii, P.V. Snytnikov, S.A. Kuznetsov, V.A. Sobyanin, 2011, published in Kataliz v Promyshlennosti.
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Semin, G.L., Dubrovskii, A.R., Snytnikov, P.V. et al. Using catalysts based on molybdenum and tungsten carbides in the water-gas shift reaction. Catal. Ind. 4, 59–66 (2012). https://doi.org/10.1134/S2070050412010102
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DOI: https://doi.org/10.1134/S2070050412010102