Skip to main content
Log in

Polymerization of higher α-olefins with the catalytic system (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-bis(perfluorophenyldimethanolate) titanium(IV) dichloride-organoaluminum compound

  • Catalysis
  • Published:
Polymer Science Series B Aims and scope Submit manuscript

Abstract

The catalytic activity of the titanium(IV) dichloride complex with the (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-bis(perfluorophenyldimethanol) ligand in the presence of a cocatalyst (polymethylaluminoxane, triethylaluminum, or triisobutylaluminum) in the polymerization of higher α-olefins (1-hexene, 1-octene, 1-decene) is investigated. It is shown that, depending on the types of cocatalyst and monomer and the molar ratio of components of the catalytic system, high- or ultrahigh-molecular-mass poly(α-olefins) with M w = (4 × 105)−(3 × 106) can be prepared. The chain microstructure of polyhexene is examined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. D. Ittel, L. K. Johnson, and M. Brookhart, Chem. Rev. 100, 1169 (2000).

    Article  CAS  Google Scholar 

  2. V. C. Gibson and S. K. Spitzmesser, Chem. Rev. 103, 283 (2003).

    Article  CAS  Google Scholar 

  3. H. Makio, N. Kashiwa, and T. Fujita, Adv. Synth. Catal. 344, 1 (2002).

    Article  Google Scholar 

  4. H. Makio and T. Fujita, Acc. Chem. Res. 42, 1532 (2009).

    Article  CAS  Google Scholar 

  5. M. Lamberti, M. Mazzeo, D. Pappalardo, and C. Pellecchia, Coord. Chem. Rev. 253, 2082 (2009).

    Article  CAS  Google Scholar 

  6. K. P. Brylyakov, Usp. Khim. 76, 279 (2007).

    Google Scholar 

  7. N. Matsukawa, S. Ishii, R. Furuyama, et al., e-Polymers, No. 021 (2003).

  8. Y. Yoshida, S. Matsui, and T. Fujita, J. Organomet. Chem. 690, 4382 (2005).

    Article  CAS  Google Scholar 

  9. T. Matsugi and T. Fujita, Chem. Soc. Rev. 37, 1264 (2008).

    Article  CAS  Google Scholar 

  10. J. D. Scollard and D. H. McConville, J. Am. Chem. Soc. 118, 10008 (1996).

    Article  CAS  Google Scholar 

  11. J. D. Scollard, D. H. McConville, N. C. Payne, and J. J. Vittal, Macromolecules 29, 5241 (1996).

    Article  CAS  Google Scholar 

  12. J. D. Scollard, D. H. McConville, J. J. Vittal, and N. C. Payne, J. Mol. Catal. A 128, 201 (1998).

    Article  CAS  Google Scholar 

  13. R. Manivannan and G. Sandararajan, Macromolecules 35, 7883 (2002).

    Article  CAS  Google Scholar 

  14. M. Mazzeo, M. Lamberti, D. Pappalardo, et al., J. Mol. Catal. A 297, 9 (2009).

    Article  CAS  Google Scholar 

  15. A. Vanderlinden, C. J. Schaverien, N. Meijboom, et al., J. Am. Chem. Soc. 117, 3008 (1995).

    Article  CAS  Google Scholar 

  16. E. P. Talzi, D. E. Babushkin, N. V. Semikolenova, et al., Kinet. Katal. 42, 165 (2001).

    Article  Google Scholar 

  17. K. P. Bryliakov, N. V. Semikolenova, V. A. Zakharov, and E. P. Talsi, Organometallics 23, 5375 (2004).

    Article  CAS  Google Scholar 

  18. S. Wang, D. Liu, R. Huang, et al., J. Mol. Catal. A 245, 122 (2006).

    Article  CAS  Google Scholar 

  19. D. Liu, S. Wang, H. Wang, and W. Chen, J. Mol. Catal. A 246, 53 (2006).

    Article  CAS  Google Scholar 

  20. H. Bando, Y. Nakayama, Y. Sonobe, and T. Fujita, Macromol. Rapid Commun. 24, 732 (2003).

    Article  CAS  Google Scholar 

  21. A. N. Panin, Z. M. Dzhabieva, P. M. Nedorezova, et al., J. Polym. Sci., Part A: Polym. Chem. 39, 1915 (2001).

    Article  CAS  Google Scholar 

  22. N. M. Bravaya, A. N. Panin, E. E. Faingold, et al., J. Polym. Sci., Part A: Polym. Chem. 48, 2934 (2010).

    Article  CAS  Google Scholar 

  23. Yu. N. Belokon’, S. Ch. Gagieva, T. A. Sukhova, et al., Izv. Akad. Nauk, Ser. Khim., No. 10, 2275 (2005).

  24. L. A. Rishina, N. M. Galashina, S. Ch. Gagieva, et al., Polymer Science, Ser. A 50, 110 (2008) [Vysokomol. Soedin., Ser. A 50, 208 (2008)].

    Google Scholar 

  25. A. Hafner, R. O. Duthaler, R. Marti, et al., J. Am. Chem. Soc. 114, 2321 (1992).

    Article  CAS  Google Scholar 

  26. T. Asakura, M. Demura, and Y. Nishiyama, Macromolecules 24, 2334 (1991).

    Article  CAS  Google Scholar 

  27. X. Zhao, G. Odian, and A. Rossi, J. Polym. Sci., Part A: Polym. Chem. 38, 3802 (2000).

    Article  CAS  Google Scholar 

  28. L. Resconi, L. Cavallo, A. Fait, and F. Piemontesi, Chem. Rev. 100, 1253 (2000).

    Article  CAS  Google Scholar 

  29. J. Saito, M. Onda, S. Matsui, et al., Macromol. Rapid Commun. 23, 1118 (2002).

    Article  CAS  Google Scholar 

  30. S. Ch. Gagieva, T. A. Sukhova, D. V. Savinov, et al., Izv. Akad. Nauk, Ser. Khim., No. 8, 1605 (2003).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to B. M. Bulychev.

Additional information

Original Russian Text © S.Ch. Gagieva, V.A. Tuskaev, O.V. Smirnova, S.S. Galibeev, B. M. Bulychev, N.M. Bravaya, 2011, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2011, Vol. 53, No. 6, pp. 935–942.

This work was supported by the Russian Foundation for Basic Research, project nos. 09-03-01060-a and 09-03-12265-ofi_m.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gagieva, S.C., Tuskaev, V.A., Smirnova, O.V. et al. Polymerization of higher α-olefins with the catalytic system (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-bis(perfluorophenyldimethanolate) titanium(IV) dichloride-organoaluminum compound. Polym. Sci. Ser. B 53, 299–306 (2011). https://doi.org/10.1134/S1560090411060042

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1560090411060042

Keywords

Navigation