Abstract
The catalytic activity of the titanium(IV) dichloride complex with the (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-bis(perfluorophenyldimethanol) ligand in the presence of a cocatalyst (polymethylaluminoxane, triethylaluminum, or triisobutylaluminum) in the polymerization of higher α-olefins (1-hexene, 1-octene, 1-decene) is investigated. It is shown that, depending on the types of cocatalyst and monomer and the molar ratio of components of the catalytic system, high- or ultrahigh-molecular-mass poly(α-olefins) with M w = (4 × 105)−(3 × 106) can be prepared. The chain microstructure of polyhexene is examined.
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Original Russian Text © S.Ch. Gagieva, V.A. Tuskaev, O.V. Smirnova, S.S. Galibeev, B. M. Bulychev, N.M. Bravaya, 2011, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2011, Vol. 53, No. 6, pp. 935–942.
This work was supported by the Russian Foundation for Basic Research, project nos. 09-03-01060-a and 09-03-12265-ofi_m.
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Gagieva, S.C., Tuskaev, V.A., Smirnova, O.V. et al. Polymerization of higher α-olefins with the catalytic system (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-bis(perfluorophenyldimethanolate) titanium(IV) dichloride-organoaluminum compound. Polym. Sci. Ser. B 53, 299–306 (2011). https://doi.org/10.1134/S1560090411060042
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DOI: https://doi.org/10.1134/S1560090411060042