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Polymers based on ionic monomers with side phosphonate groups

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Abstract

A number of new ionic vinyl monomers composed of 1-vinylimidazolium cation with diethoxy- and dihydroxyphosphoryl groups and various anions—Br−, (CN)2N−, and (CF3SO2)2N−—are synthesized. The free-radical polymerization of the monomers in solutions of molecular and ionic solvents yields new polymer analogs of ionic liquids, and their molecular-mass characteristics, solubility, heat resistance, thermal stability, and electrical conductivity are estimated. It is shown that the incorporation of bulky phosphorylalkyl side substituents into the vinylimidazolium polycation causes a decrease in the glass-transition temperature and an increase in the ionic conductivity of polymer salts. The highest ionic conductivity (2.6 × 10−5 S/cm at 25°C) is exhibited by the polymer with the (CN)2N− anion.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    O. A. Mel’nik, A. S. Shaplov, E. I. Lozinskaya, N. A. Popova, M. V. Makarov, I. L. Odinets, K. A. Lysenko, G. I. Timofeeva & Ya. S. Vygodskii

  2. Faculty of Physics, Moscow State University, Moscow, 119992, Russia

    I. A. Malyshkina

Authors
  1. O. A. Mel’nik
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  2. A. S. Shaplov
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  3. E. I. Lozinskaya
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  4. N. A. Popova
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  5. M. V. Makarov
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  6. I. L. Odinets
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  7. K. A. Lysenko
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  8. G. I. Timofeeva
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  9. I. A. Malyshkina
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  10. Ya. S. Vygodskii
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Corresponding author

Correspondence to O. A. Mel’nik.

Additional information

Original Russian Text © O.A. Mel’nik, A.S. Shaplov, E.I. Lozinskaya, N.A. Popova, M.V. Makarov, I.L. Odinets, K.A. Lysenko, G.I. Timofeeva, I.A. Malyshkina, Ya.S. Vygodskii, 2010, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2010, Vol. 52, No. 6, pp. 1018–1029.

This work was supported by the Russian Foundation for Basic Research, project nos. 07-03-12196_ofi-a, 07-03-00541_a, and 08-03-00766_a.

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Mel’nik, O.A., Shaplov, A.S., Lozinskaya, E.I. et al. Polymers based on ionic monomers with side phosphonate groups. Polym. Sci. Ser. B 52, 316–326 (2010). https://doi.org/10.1134/S1560090410050088

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  • DOI: https://doi.org/10.1134/S1560090410050088

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