Abstract
2-(2-furyl)phenanthro[9,10-d]oxazole was synthesized by the reaction of 9,10-phenanthrenequinoneimine and furan-2-carbaldehyde in ethanol. Reactions of electrophilic substitution of this compound were investigated (nitration, bromination, sulfurization, formylation, acylation). Depending on the reaction conditions the electrophile attacks either the furan ring or the phenanthrene fragment.
Similar content being viewed by others
References
Krasovitskii, B.M., Pereyaslava, D.G., and Yushko, E.T., Monokrystally, stsintillyatory i organicheskie luminofory (Monocrystals, Scintillators and Organic Luminophors), Khar’kov: Izd. VNII monokristallov, 1968, Part 4.
Doroshenko, A.O., Patesenker, L.D., and Baumer, V.N., Molekular Eng., 1994, vol. 3, p. 343.
Krasovitskii, B.M. and Afanasiadi, L.M., Preparativnaya khimiya luminoforov (Preparative Chemistry of Luminophors), Khar’kov: Folio, 1997.
Roshal, A.D., Luk’yanov, B.S., and El’chaninov, M.M., Russ. J. Phys. Chem. A., 2003, vol. 77, p. 1709.
Pechkin, A.A., El’chaninov, M.M., and Stoyanov, V.M., Russ. J. Org. Chem., 2002, vol. 38, p. 726.
Stein, C.W.C., and Day, A.R., J. Am. Chem. Soc., 1942, vol. 64, p. 2567.
Tsibizov, Yu.N., Pozharskii, F.T., Simonov, A.M., Knyazhanskii, M.I., and Stryukov, M.B., USSR Inventor’s Certificate no. 413861, 1974; Byull. Izobret., 1975, no. 31.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A. Aleksandrov, M.M. Elchaninov, 2015, published in Zhurnal Organicheskoi Khimii, 2015, Vol. 51, No. 5, pp. 676–678.
Rights and permissions
About this article
Cite this article
Aleksandrov, A.A., Elchaninov, M.M. Synthesis and reactivity of 2-(2-furyl)phenanthro[9,10-d]oxazole. Russ J Org Chem 51, 657–659 (2015). https://doi.org/10.1134/S1070428015050127
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070428015050127