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Design of postmetallocene catalytic systems of arylimine type for olefi n polymerization: XV. Synthesis of (N-Aryl)salicylaldimine ligands containing a but-3-enyloxy group and their complexes with titanium(IV) dichloride

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Abstract

A series of (N-aryl)salicylaldimines was synthesized by the reaction of salicylaldehydes substituted in the positions 3 and 5 by bulky tert-butyl or α-cumyl groups with hydrochlorides of o-, m-, and p-(but-3-enyloxy) aniline in the presence of triethylamine. The obtained compounds formed by the reaction with TiCl2(OPr-i)2 complexes of titanium(IV) dichloride L2TiCl2.

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Correspondence to I. I. Oleinik.

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Original English Text © I.I. Oleinik, I V. Oleinik, S.S. Ivanchev, G.A. Tolstikov, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 8, pp. 1168–1173.

For Communication XIV, see [1].

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Oleinik, I.I., Oleinik, I.V., Ivanchev, S.S. et al. Design of postmetallocene catalytic systems of arylimine type for olefi n polymerization: XV. Synthesis of (N-Aryl)salicylaldimine ligands containing a but-3-enyloxy group and their complexes with titanium(IV) dichloride. Russ J Org Chem 49, 1150–1156 (2013). https://doi.org/10.1134/S1070428013080095

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