Skip to main content
SpringerLink
Log in

Sorption Recovery of Lanthanum, Iron, Aluminum, and Calcium Ions from Phosphoric Acid

  • Sorption and Ion Exchange Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Sorption recovery of lanthanum, iron(III), aluminum, and calcium ions from phosphoric acid solutions with MTC 1600 macroporous sulfonic cation exchanger under dynamic conditions was studied. Calcium suppresses the sorption of lanthanum and other elements; in its presence, the dynamic exchange capacity of the sorbent for lanthanum decreases from 53.5 to 11.8 mg g–1, and that for iron and aluminum tends to zero. In elution of lanthanum and calcium ions from the resin phase with an ammonium nitrate solution, the maximal concentration of the ions was 5.5 and 9.5 g L–1, respectively. The ratio of the calcium and lanthanum ions in the eluate is 2 times higher than that in the initial phosphoric acid solution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Sun, X., Luoё, H., Shannon, M.M., Liu, R., Hou, X., and Dai, S., J. Rare Earths, 2016, vol. 34, no. 1, pp. 77–82. https://doi.org/10.1016/S1002-0721(14)60582-2

    Article  CAS  Google Scholar 

  2. York, R.S., Dhiman, B., Travis, W., and Mano, M., Chem. Eng. J., 2016, vol. 296, pp. 102–111. https://doi.org/10.1016/j.cej.2016.03.082

    Article  CAS  Google Scholar 

  3. El-Bayaa, A.A., Badawy, N.A., Gamal, A.M., Zidan, I.H., and Mowafy, A.R., J. Hazard. Mater., 2011, vol. 190, nos. 1–3, pp. 324–329. https://doi.org/10.1016/j.jhazmat.2011.03.037

    Article  CAS  PubMed  Google Scholar 

  4. Wafa, T. and Ali, T., J. Afr. Earth Sci., 2017, vol. 129, pp. 647–658. https://doi.org/10.1016/j.jafrearsci.2017.02.008

    Article  CAS  Google Scholar 

  5. Xiao, Y., Huang, L., Long, Z., Feng, Z., and Wang, L., J. Rare Earths, 2016, vol. 34, no. 5, pp. 543–548. https://doi.org/10.1016/S1002-0721(16)60060-1

    Article  CAS  Google Scholar 

  6. Radhika, S., Nagaraju, V., Nagaphani, K.B., Lakshmi, K.M., and Ramachandra, R.B., J. Rare Earths, 2012, vol. 30, no. 12, pp. 1270–1275. https://doi.org/10.1016/S1002-0721(12)60219-1

    Article  CAS  Google Scholar 

  7. Reddy, B.R. and Kumar, J.R., Solvent Extr. Ion Exch., 2016, vol. 34, no. 3, pp. 1–15. https://doi.org/10.1080/07366299.2016.1169144

    Article  CAS  Google Scholar 

  8. Al-Thyabat, S. and Zhang, P., Miner. Proc. Extract. Metall., 2015, vol. 124, no. 3, pp. 143–150. https://doi.org/10.1179/1743285515Y.0000000002

    Article  CAS  Google Scholar 

  9. Miller, D.D., Siriwardane, R., and Mcintyre, D., J. Rare Earths, 2018, pp. 1–12. https://doi.org/10.1016/j.jre.2018.03.006

    Article  CAS  Google Scholar 

  10. Hidayah, N.N. and Abidin, S.Z., Miner. Eng., 2017, vol. 112, pp. 103–113. https://doi.org/10.1016/j.mineng.2017.07.014

    Article  CAS  Google Scholar 

  11. Kartikey, K.Y., Kinshuk, D., Singh, D.K., Anitha, M., Varshney, L., and Singh, H., Sep. Purif. Technol., 2015, vol. 143, pp. 115–124. https://doi.org/10.1016/j.seppur.2015.01.032

    Article  CAS  Google Scholar 

  12. Papkova, M.V., Kon’kova, T.V., Samieva, D.A., and Vasilenko, S.A., Russ. J. Appl. Chem., 2018, vol. 91, no. 3, pp. 379–383. https://doi.org/10.1134/S1070427218030059 

    Article  CAS  Google Scholar 

  13. Lokshin, E.P., Tareeva, O.A., and Elizarova, I.R., Tr. Kol’sk. Nauchn. Tsentra Ross. Akad. Nauk. Khim. Materiaoloved., 2018, no. 1(9), issue 2, part 1. https://doi.org/10.25702/ksc.2307-5252.2018.9.1.175-180

  14. Kon’kova, T.V., C.N. Quynh, and Papkova, M.V., Tsvetn. Met., 2018, no. 9, pp. 54–57. https://doi.org/10.17580/tsm.2018.09.08

    Article  CAS  Google Scholar 

  15. Papkova, M.V., Mikhailichenko, A.I., Kon’kova, T.V., and Saikina, O.Yu., Tsvetn. Met., 2016, no. 8, pp. 57–62. https://doi.org/10.17580/tsm.2016.08.08

    Article  CAS  Google Scholar 

  16. Chirkst, D.E., Dibrov, I.A., Cheremisina, O.V., and Melikhov, I.V., Zh. Fiz. Khim., 1991, vol. 65, no. 8, pp. 2180–2183.

    Google Scholar 

  17. Lokshin, E.P., Tareeva, O.A., and Elizarov, I.R., Russ. J. Appl. Chem., 2016, vol. 89, no. 4, pp. 570–576. https://doi.org/10.1134/S107042721604008X 

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    T. V. Kon’kova & Trinh Nguyen Quynh

Authors
  1. T. V. Kon’kova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Trinh Nguyen Quynh
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. V. Kon’kova.

Ethics declarations

The authors declare that they have no conflict of interest.

Additional information

Translated from Zhurnal Prikladnoi Khimii, No. 12, pp. 1774–1778, December, 2020 https://doi.org/10.31857/S0044461820120087

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kon’kova, T.V., Quynh, T.N. Sorption Recovery of Lanthanum, Iron, Aluminum, and Calcium Ions from Phosphoric Acid. Russ J Appl Chem 93, 1868–1872 (2020). https://doi.org/10.1134/S1070427220120083

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427220120083

Keywords:

Search

Navigation