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Preparation and Properties of Frost-Resistant Materials Based on Compounds of Oligoether Urethane Epoxides and Diglycidyl Urethane

  • Macromolecular Compounds and Polymeric Materials
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Abstract

A procedure was suggested for preparing epoxy ether urethane oligomers via intermediate oligodiisocyanates with increased content of the starting 2,4-toluene diisocyanate. The procedure allows preparation of epoxy-containing oligomers with appreciable fraction of low-molecular-mass diglycidyl urethane. The presence of diglycidyl urethane in the binder enhances not only the adhesion but also the strength of the cured material without significantly affecting the glass transition point of the binder. Elastic materials prepared by curing the compounds studied with cylcoaliphatic amines exhibit enhanced levels of strength and low-temperature elasticity.

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References

  1. Chen, D.S., Ma, C.C.M., Hsia, H.C., Wang, W.N., and Lin, S.R., J. Appl. Polym. Sci., 1994, vol. 51, no. 7, pp. 1199–1206.

    Article  CAS  Google Scholar 

  2. Hsia, H.C., Ma, C.C.M., Li, M.S., Li, Y.S., and Chen, D.S., J. Appl. Polym. Sci., 1994, vol. 52, no. 8, pp. 1137–1151.

    Article  CAS  Google Scholar 

  3. Yeganeh, H., Mehdipour-Ataei, S., and Ghaffari, M., High Perform. Polym. 2008, vol. 20, no. 2, pp. 126–145.

    Article  CAS  Google Scholar 

  4. Mustafin, V.R., Shukurdzhiev, M.S., and Magrunov, F.A., Plast. Massy 1992, no. 2, pp. 8–9.

    Google Scholar 

  5. Pavlova, M., Draganova, M., and Kabaivanov, V., Polym. Commun. 1988, vol. 29, no. 3, pp. 80–82.

    CAS  Google Scholar 

  6. Patent RU 2291176, Publ. 2007.

  7. Sidorov, O.I., Milekhin, Yu.M., Matveev, A.A., Poisova, T.P., Bykova, K.A., and Sadchikov, N.V., Keli. Germet. Tekhnol. 2012, no. 9, pp. 15–21.

    Google Scholar 

  8. Elchueva, A.D., Nazipov, M.M., Tabachkov, A.A., and Liakumovich, A.G., Russ. J. Appl. Chem. 2003, vol. 76, no. 3, pp. 487–490.

    Article  CAS  Google Scholar 

  9. Skripinets, A.V., Danchenko, Yu.M., and Kabus’, A.V., Vost.-Evr. Zh. Pered. Tekhnol. 2015, no. 3 (11), pp. 4–8.

    Google Scholar 

  10. Hsia, H.C., Ma, C.C.M., and Chen, D.S., Macromol. Mater. Eng. 1994, vol. 220, no. 1, pp. 133–149.

    CAS  Google Scholar 

  11. Yeganeh, H., Jamshidi, H., and Jamshidi, S., Polym. Int. 2007, vol. 56, no. 1, pp. 41–49.

    Article  CAS  Google Scholar 

  12. Li, C.Y., Chen, J.H., Chien, P.C., Chiu, W.Y., Chen, R.S., and Don, T.M., Polym. Eng. Sci. 2007, vol. 47, no. 5, pp. 625–632.

    Article  CAS  Google Scholar 

  13. Chen, W.H., Chen, P.C., Wang, S.C., Yeh, J.T., Huang, C.Y., and Chen, K.N., J. Polym. Res., 2009, vol. 16, pp. 601–630.

    Article  CAS  Google Scholar 

  14. Madhavan, K. and Reddy, B.S.R., J. Polym. Sci., Part A: Polym. Chem., 2006, vol. 44, no. 9, pp. 2980–2989.

    Article  CAS  Google Scholar 

  15. Edwards, P.A., Striemer, G., and Webster, D.C., JCT Res., 2005, vol. 2, no. 7, pp. 517–527.

    CAS  Google Scholar 

  16. Fedoseev, M.S., Tereshatov, V.V., and Derzhavinskaya, L.F., Russ. J. Appl. Chem. 2010, vol. 83, no. 8, pp. 1367–1371.

    Article  CAS  Google Scholar 

  17. Makarova, M.A., Slobodinyuk, A.I., Tereshatov, V.V., Volkova, E.R., and Kisel’kov, D.M., Polym. Sci., Ser. D, 2014, vol. 7, no. 3, pp. 166–169.

    CAS  Google Scholar 

  18. Strel’nikov, V.N., Senichev, V.Yu., Slobodinyuk, A.I., Savchuk, A.V., Volkova, E.R., Makarova, M.A., Nechaev, A.I., Krasnosel’skikh, S.F., and Ukhin, K.O., Russ. J. Appl. Chem. 2018, vol. 91, no. 3, pp. 463–468.

    Article  Google Scholar 

  19. Savchuk, A.V., Tereshatov, V.V., and Slobodinyuk, A.I., Polym. Sci., Ser. D, 2018, vol. 11, no. 3, pp. 252–255.

    CAS  Google Scholar 

  20. Slobodinyuk, A.I., Pinchuk, A.V., Vnutskikh, Zh.A., and Tereshatov, V.V., Klei. Germet. Tekhnol. 2016, no. 8, pp. 14–18.

    Google Scholar 

  21. Socrates, G., Infrared and Raman Characteristic Group Frequencies: Tables and Charts, Wiley, 2001.

    Google Scholar 

  22. Tarasevich, B.N., IK spektry osnovnykh klassov organicheskikh soedinenii (IR Spectra of the Main Classes of Organic Compounds), Moscow: Spravochnye Materialy, 2012.

    Google Scholar 

  23. Guadagno, L., Vertuccio, L., Sorrentino, A., Raimondo, M., Naddeo, C., Vittoria, V., Iannuzzo, G., Calvi, E., and Russo, S., Carbon 2009, vol. 47, no. 10, pp. 2419–2430.

    Article  CAS  Google Scholar 

  24. Piau, J.M. and Piau, M., J. Rheol., 2005, vol. 49, no. 6, pp. 1539–1550.

    Article  CAS  Google Scholar 

  25. Szycher, M., Szycher’s Handbook of Polyurethanes, Boca Raton: CRC, 2013, 2nd ed.

    Google Scholar 

  26. Mathew, A., Kurmvanshi, S., Mohanty, S., and Nayak, S.K., Polym. Int. 2017, vol. 66, no. 11, pp. 1546–1554.

    Article  CAS  Google Scholar 

  27. Huang, S.L. and Lai, J.Y., J. Membr. Sci., 1995, vol. 105, nos. 1–2, pp. 137–145.

    Article  CAS  Google Scholar 

  28. Blake, J., Jang, W., Anderson, R., Macosko, C., and Macosko, C.W., Polym. Eng. Sci. 1987, vol. 27, no. 16, pp. 1236–1242.

    Article  CAS  Google Scholar 

  29. Hepburn, C., Polyurethane Elastomers, New York: Elsevier, 1992.

    Book  Google Scholar 

  30. Volkova, E.R., Tereshatov, V.V., and Karmanov, V.I., Russ. J. Appl. Chem. 2011, vol. 84, no. 8, pp. 1414–1417.

    Article  CAS  Google Scholar 

  31. Ahn, T.O., Jung, S.U., Jeong, H.M., and Lee, S.W., J. Appl. Polym. Sci., 1994, vol. 51, no. 1, pp. 43–49.

    Article  CAS  Google Scholar 

  32. Tereshatov, V.V., Makarova, M.A., Senichev, V.Y., Volkova, E.R., Vnutskikh, Z.A., and Slobodinyuk, A.I., Colloid Polym. Sci. 2015, vol. 293, no. 1, pp. 153–164.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Technical Chemistry, Branch of the Perm Federal Research Center, Ural Branch, Russian Academy of Sciences, Perm, Russia

    V. N. Strel’nikov, V. Yu. Senichev, A. I. Slobodinyuk, A. V. Savchuk, E. R. Volkova, M. A. Makarova, Yu. L. Belov, L. F. Derzhavinskaya & D. G. Selivanova

Authors
  1. V. N. Strel’nikov
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  2. V. Yu. Senichev
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  3. A. I. Slobodinyuk
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  4. A. V. Savchuk
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  5. E. R. Volkova
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  6. M. A. Makarova
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  7. Yu. L. Belov
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  8. L. F. Derzhavinskaya
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  9. D. G. Selivanova
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Correspondence to A. I. Slobodinyuk.

Additional information

Original Russian Text © V.N. Strel’nikov, V.Yu. Senichev, A.I. Slobodinyuk, A.V. Savchuk, E.R. Volkova, M.A. Makarova, Yu.L. Belov, L.F. Derzhavinskaya, D.G. Selivanova, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 12, pp. 1708−1716.

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Strel’nikov, V.N., Senichev, V.Y., Slobodinyuk, A.I. et al. Preparation and Properties of Frost-Resistant Materials Based on Compounds of Oligoether Urethane Epoxides and Diglycidyl Urethane. Russ J Appl Chem 91, 1937–1944 (2018). https://doi.org/10.1134/S1070427218120042

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  • DOI: https://doi.org/10.1134/S1070427218120042

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