Abstract
Complex formation of zinc(II) with citric acid in acidic medium was studied by pH-potentiometric titration at various metal to acid ratios. The speciation diagrams of the complexes in relation to pH were plotted, and the stability constants of the complexes were determined. Precursors of the synthesis of metal oxide materials were prepared at two reactant ratios. A scheme of the precursor thermal decomposition based on data of derivatography and IR spectroscopy was suggested, and the compositions of compounds formed during decomposition were determined.
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Ookubo, A., Ooi, K., and Hayashi, H., Langmuir, 1993, vol. 9, no. 5, pp. 1418–1422.
Materials for Lithium Ion Batteries, Julien, C. and Stoynov, Z., Eds., NATO Sci. Ser. 3, High Technology, Dordrecht: Kluwer Academic, 2000, vol. 85.
Weidenkaff, A., Ebbinghaus, S.G., and Lippert, T., J. Chem. Mater., 2002, vol. 14, no. 4, pp. 1797–1805.
Tas, A.C., Majewski, P.J., and Aldinger, F., J. Am. Ceram. Soc., 2000, vol. 83, no. 12, pp. 2954–2960.
Alonso, J.A., Martinez-Lopez, M.J., Casais, M.T., et al., J. Chem. Mater., 1999, vol. 11, no. 9, pp. 2463–2469.
US Patent 3 330 697.
Todorovsky, D.S., Dumanova, D.G., Todorovska, R.V., and Getsova, M.M., Croat. Chem. Acta, 2002, vol. 75, no. 1, pp. 155–164.
Farbun, I.A., Romanova, I.V., and Kirillov, S.A., Abstracts of Papers, XVI Ukrains’ka konferentsiya po neorganichnoi khimii (XVI Ukrainian Conf. on Inorganic Chemistry), Uzhgorod, 2004, pp. 32–33.
Romanova, I.V., Zazhigalov, V.A., and Kirillov, S.A., Abstracts of Papers, Ukrainian-Polish Symp. “Theoretical and Experimental Studies of Interfacial Phenomena and Their Technological Applications,” Sandomierz (Poland), September 5–9, 2005, pp. 239–240.
Zazhigalov, V.A., Stoch, J., Kowal, A., et al., Abstracts of Papers, XXXVII Ogolnopolskie kolokwium katalityczne, Krakow, 2005, pp. 154–155.
Delimaris, D., Kirillov, S.A., Romanova, I.V., et al., Abstracts of Papers, 7th European Congr. on Catalysis, Sofia (Bulgaria), August 28–September 1, 2005, p. 272.
Kirillov, S.A., Romanova, I.V., and Farbun, I.A., NATO-CARWC “New Carbon Based Materials for Electrochemical Energy Storage Systems”, Dordrecht: Kluwer Academic, 2006, pp. 495–504.
Zhong Lin Wang, J. Phys., Condens. Matter, 2004, vol. 16, no. 25, pp. 829–858.
Ohta, H. and Hosono, H., Mater. Today, 2004, vol. 7, no. 6, pp. 42–51.
Schwarzenbach, G. and Flaschka, H., Die komplexometrische Titration, Stuttgart: Enke, 1965.
Alekseev, V.N., Kolichestvennyi analiz (Quantitative Analysis), Moscow: Khimiya, 1972.
Kholin, Yu.V., Konyaev, D.S., and Mernyi, S.A., Vestn. Khar’k. Nats. Univ., Khim., 1999, no. 437, issue 3 (26), pp. 17–35.
Migal’, P.K. and Sychev, A.Ya., Zh. Neorg. Khim., 1958, vol. 3, no. 2, pp. 314–324.
Happe, J.A., J. Am. Chem. Soc., 1973, vol. 95, no. 18, pp. 6232–6237.
Daniele, P. and Ostacoli, G., Ann. Chim. (Rome), 1977, vol. 67, no. 1, pp. 37–41.
Campi, E., Ostacoli, G., Meirone, M., and Saini, G., J. Inorg. Nucl. Chem., 1964, vol. 26, no. 4, pp. 553–564.
Martin, R.B., Antimicrob. Agents Chemother., 1988, vol. 32, no. 4, pp. 608–609.
Lur’e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook on Analytical Chemistry), Moscow: Goskhimizdat, 1962.
Albert, A. and Serjeant, E., Ionization Constants of Acids and Bases. A Laboratory Manual, New York: Wiley, 1962.
Martell, A.E. and Calvin. M., Chemistry of the Metal Chelate Compounds, New York: Prentice-Hall, 1953.
Van Werde, K., Mondelaers, D., Vanhoyland, G., et al., J. Mater. Sci., 2002, vol. 37, no. 1, pp. 81–88.
Kharitonov, Yu.Ya. and Alikhanova, Z.M., Radiokhimiya, 1964, vol. 6, no. 6, pp. 702–713.
Jung, C., J. Mol. Recognit., 2000, vol. 13, no. 6, pp. 325–351.
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Original Russian Text © I.A. Farbun, I.V. Romanova, T.E. Terikovskaya, D.I. Dzanashvili, S.A. Kirillov, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 11, pp. 1773–1778.
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Farbun, I.A., Romanova, I.V., Terikovskaya, T.E. et al. Complex formation in the course of synthesis of zinc oxide from citrate solutions. Russ J Appl Chem 80, 1798–1803 (2007). https://doi.org/10.1134/S1070427207110031
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DOI: https://doi.org/10.1134/S1070427207110031