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Complex formation in the course of synthesis of zinc oxide from citrate solutions

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Complex formation of zinc(II) with citric acid in acidic medium was studied by pH-potentiometric titration at various metal to acid ratios. The speciation diagrams of the complexes in relation to pH were plotted, and the stability constants of the complexes were determined. Precursors of the synthesis of metal oxide materials were prepared at two reactant ratios. A scheme of the precursor thermal decomposition based on data of derivatography and IR spectroscopy was suggested, and the compositions of compounds formed during decomposition were determined.

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References

  1. Ookubo, A., Ooi, K., and Hayashi, H., Langmuir, 1993, vol. 9, no. 5, pp. 1418–1422.

    Article  CAS  Google Scholar 

  2. Materials for Lithium Ion Batteries, Julien, C. and Stoynov, Z., Eds., NATO Sci. Ser. 3, High Technology, Dordrecht: Kluwer Academic, 2000, vol. 85.

    Google Scholar 

  3. Weidenkaff, A., Ebbinghaus, S.G., and Lippert, T., J. Chem. Mater., 2002, vol. 14, no. 4, pp. 1797–1805.

    Article  CAS  Google Scholar 

  4. Tas, A.C., Majewski, P.J., and Aldinger, F., J. Am. Ceram. Soc., 2000, vol. 83, no. 12, pp. 2954–2960.

    Article  CAS  Google Scholar 

  5. Alonso, J.A., Martinez-Lopez, M.J., Casais, M.T., et al., J. Chem. Mater., 1999, vol. 11, no. 9, pp. 2463–2469.

    Article  CAS  Google Scholar 

  6. US Patent 3 330 697.

  7. Todorovsky, D.S., Dumanova, D.G., Todorovska, R.V., and Getsova, M.M., Croat. Chem. Acta, 2002, vol. 75, no. 1, pp. 155–164.

    CAS  Google Scholar 

  8. Farbun, I.A., Romanova, I.V., and Kirillov, S.A., Abstracts of Papers, XVI Ukrains’ka konferentsiya po neorganichnoi khimii (XVI Ukrainian Conf. on Inorganic Chemistry), Uzhgorod, 2004, pp. 32–33.

  9. Romanova, I.V., Zazhigalov, V.A., and Kirillov, S.A., Abstracts of Papers, Ukrainian-Polish Symp. “Theoretical and Experimental Studies of Interfacial Phenomena and Their Technological Applications,” Sandomierz (Poland), September 5–9, 2005, pp. 239–240.

  10. Zazhigalov, V.A., Stoch, J., Kowal, A., et al., Abstracts of Papers, XXXVII Ogolnopolskie kolokwium katalityczne, Krakow, 2005, pp. 154–155.

  11. Delimaris, D., Kirillov, S.A., Romanova, I.V., et al., Abstracts of Papers, 7th European Congr. on Catalysis, Sofia (Bulgaria), August 28–September 1, 2005, p. 272.

  12. Kirillov, S.A., Romanova, I.V., and Farbun, I.A., NATO-CARWC “New Carbon Based Materials for Electrochemical Energy Storage Systems”, Dordrecht: Kluwer Academic, 2006, pp. 495–504.

    Book  Google Scholar 

  13. Zhong Lin Wang, J. Phys., Condens. Matter, 2004, vol. 16, no. 25, pp. 829–858.

    Article  CAS  Google Scholar 

  14. Ohta, H. and Hosono, H., Mater. Today, 2004, vol. 7, no. 6, pp. 42–51.

    Article  CAS  Google Scholar 

  15. Schwarzenbach, G. and Flaschka, H., Die komplexometrische Titration, Stuttgart: Enke, 1965.

    Google Scholar 

  16. Alekseev, V.N., Kolichestvennyi analiz (Quantitative Analysis), Moscow: Khimiya, 1972.

    Google Scholar 

  17. Kholin, Yu.V., Konyaev, D.S., and Mernyi, S.A., Vestn. Khar’k. Nats. Univ., Khim., 1999, no. 437, issue 3 (26), pp. 17–35.

  18. Migal’, P.K. and Sychev, A.Ya., Zh. Neorg. Khim., 1958, vol. 3, no. 2, pp. 314–324.

    CAS  Google Scholar 

  19. Happe, J.A., J. Am. Chem. Soc., 1973, vol. 95, no. 18, pp. 6232–6237.

    Article  CAS  Google Scholar 

  20. Daniele, P. and Ostacoli, G., Ann. Chim. (Rome), 1977, vol. 67, no. 1, pp. 37–41.

    CAS  Google Scholar 

  21. Campi, E., Ostacoli, G., Meirone, M., and Saini, G., J. Inorg. Nucl. Chem., 1964, vol. 26, no. 4, pp. 553–564.

    Article  CAS  Google Scholar 

  22. Martin, R.B., Antimicrob. Agents Chemother., 1988, vol. 32, no. 4, pp. 608–609.

    CAS  Google Scholar 

  23. Lur’e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook on Analytical Chemistry), Moscow: Goskhimizdat, 1962.

    Google Scholar 

  24. Albert, A. and Serjeant, E., Ionization Constants of Acids and Bases. A Laboratory Manual, New York: Wiley, 1962.

    Google Scholar 

  25. Martell, A.E. and Calvin. M., Chemistry of the Metal Chelate Compounds, New York: Prentice-Hall, 1953.

    Google Scholar 

  26. Van Werde, K., Mondelaers, D., Vanhoyland, G., et al., J. Mater. Sci., 2002, vol. 37, no. 1, pp. 81–88.

    Article  Google Scholar 

  27. Kharitonov, Yu.Ya. and Alikhanova, Z.M., Radiokhimiya, 1964, vol. 6, no. 6, pp. 702–713.

    CAS  Google Scholar 

  28. Jung, C., J. Mol. Recognit., 2000, vol. 13, no. 6, pp. 325–351.

    Article  CAS  Google Scholar 

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Original Russian Text © I.A. Farbun, I.V. Romanova, T.E. Terikovskaya, D.I. Dzanashvili, S.A. Kirillov, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 11, pp. 1773–1778.

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Farbun, I.A., Romanova, I.V., Terikovskaya, T.E. et al. Complex formation in the course of synthesis of zinc oxide from citrate solutions. Russ J Appl Chem 80, 1798–1803 (2007). https://doi.org/10.1134/S1070427207110031

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  • DOI: https://doi.org/10.1134/S1070427207110031

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