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Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the ligand structure

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Abstract

Polymerization of ethylene at 30–70°C in the presence of catalytic systems based on titanium bis(phenoxy imine) complexes of various structures, activated with methylalumoxane, was studied. An attempt was made to systematize the effect of substituents in ligands, to find correlations, to account for the results obtained, and to reveal conditions under which the reaction occurs by the living polymerization mechanism. Some properties and structural features of the polyethylenes obtained were determined.

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Authors and Affiliations

  1. St. Petersburg Branch, Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, St. Petersburg, Russia

    M. Yu. Malinskaya, N. I. Ivancheva, I. I. Oleinik, G. A. Tolstikov & S. S. Ivanchev

  2. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    M. Yu. Malinskaya, N. I. Ivancheva, I. I. Oleinik, G. A. Tolstikov & S. S. Ivanchev

Authors
  1. M. Yu. Malinskaya
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  2. N. I. Ivancheva
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  3. I. I. Oleinik
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  4. G. A. Tolstikov
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  5. S. S. Ivanchev
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Additional information

Original Russian Text © M.Yu. Malinskaya, N.I. Ivancheva, I.I. Oleinik, G.A. Tolstikov, S.S. Ivanchev, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 9, pp. 1479–1488.

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Malinskaya, M.Y., Ivancheva, N.I., Oleinik, I.I. et al. Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the ligand structure. Russ J Appl Chem 80, 1515–1522 (2007). https://doi.org/10.1134/S1070427207090145

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  • DOI: https://doi.org/10.1134/S1070427207090145

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