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Complexes of rhodium(III) with N-functionalized calix[4]resorcinolol

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Abstract

Singularities of the rhodium trichloride reaction with calix[4]resorcinol functionalized with CH2N· (CH3)2 groups in ethanol on the upper rim of the molecule, and also of calix[4]resorcinol with ethanol solution of rhodium trichloride saturated with nitrogen monoxide were studied. Neutral complex compounds separated in the solid form were characterized by IR spectroscopy, Raman spectroscopy, 1H NMR, ESR, X-ray electron spectroscopy, electronic spectroscopy, and conductometry. Quantum-chemical calculations were performed on the basis of the density functional method in order to determine the geometric structure and energy characteristics of the complex compound and the zwitter-ion form of the ligand.

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Authors and Affiliations

  1. Kazan State Technological University, ul. K. Marksa 68, Kazan, Tatarstan, 420015, Russia

    E. V. Guseva, T. T. Zinkicheva & E. I. Grishin

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    V. I. Morozov & A. D. Voloshina

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  1. E. V. Guseva
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  2. V. I. Morozov
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  3. T. T. Zinkicheva
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  4. A. D. Voloshina
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  5. E. I. Grishin
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Correspondence to E. V. Guseva.

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Original Russian Text © E.V. Guseva, V.I. Morozov, T.T. Zinkicheva, A.D. Voloshina, E.I. Grishin, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 8, pp. 1233–1243.

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Guseva, E.V., Morozov, V.I., Zinkicheva, T.T. et al. Complexes of rhodium(III) with N-functionalized calix[4]resorcinolol. Russ J Gen Chem 82, 1323–1333 (2012). https://doi.org/10.1134/S1070363212080014

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  • DOI: https://doi.org/10.1134/S1070363212080014

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