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Synthesis of Coordination Polymers from the Heterometallic Carboxylate Complexes with Chelating N-Donor Ligands

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Abstract

New trinuclear Cd–Ln molecular complexes [EuCd2(O2CC6F5)6(NO3)(Bipy)2] (I, Bipy is 2,2'-bipyridine) and [LnCd2(Bzo)6(NO3)(Phen)2] · 4MeCN (Ln = Tb (II), Eu (III), Bzo is anion of 3,5-di-tert-butylbenzoic acid, Phen is 1,10-phenanthroline) are studied. Their structures are determined by X-ray structure analysis (СIF files CCDC nos. 1938125 (I), 1938124 (II)) or by X-ray diffraction analysis (III), and the photoluminescence properties are studied. The reactions of complexes I and II with terephthalic acid (H2Bdc) are accompanied by the destruction of the heterometallic molecules to form 2D coordination polymers [Cd3(Bbdc)3(Bipy)2]3n · 4nMeCN · nH2O (IV) and [Cd2(Bdc)2(Phen)2]n · 2nDMF (V) (СIF files CCDC nos. 1938126 and 1937492, respectively).

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ACKNOWLEDGMENTS

X-ray structure analysis (for compounds I and II), X-ray diffraction analysis, IR spectroscopy, and elemental analysis of the synthesized compounds were carried out using the equipment of the Center for Collective Use of Physical Methods of Investigation at the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) in the framework of the state task of the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) in the area of basic research. The study of the structure of complex IV was supported by the Ministry of Science and Higher Education of the Russian Federation using the scientific equipment of the Center of Molecular Structure Investigation at the Nesmeyanov Institute of Organoelement Compounds (Russian Academy of Sciences). The data on the structure of compound V were obtained on the X-ray beam of the Belok station of the Kurchatov Center of Synchrotron Radiation at the Kurchatov Institute Russian Research Center.

Funding

The synthesis and study of complexes I–III were supported by the Russian Science Foundation (project no. 16-13-10537). The synthesis and study of complexes IV and V were supported by the Russian Foundation for Basic Research (project no. 18-29-04043). E.V. Aleksandrov acknowledges the Council for Grants of the President of the Russian Federation (grant no. MK-415.2019.3) for financial support of the development of topological methods of analysis.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    M. A. Shmelev, N. V. Gogoleva, D. A. Makarov, M. A. Kiskin, I. A. Yakushev, G. G. Aleksandrov, A. A. Sidorov & I. L. Eremenko

  2. Kurchatov Institute Russian Research Center, 123182, Moscow, Russia

    I. A. Yakushev

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    F. M. Dolgushin, E. A. Varaksina & I. V. Taidakov

  4. Lebedev Physical Institute, Russian Academy of Sciences, 119991, Moscow, Russia

    E. A. Varaksina & I. V. Taidakov

  5. Moscow Institute of Physics and Technology (National Research University), 141700, Dolgoprudnyi, Moscow oblast, Russia

    I. V. Taidakov

  6. Samara National Research University, Samara, Russia

    E. V. Aleksandrov

  7. Samara State Technical University, Samara, Russia

    E. V. Aleksandrov

Authors
  1. M. A. Shmelev
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  2. N. V. Gogoleva
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  3. D. A. Makarov
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  4. M. A. Kiskin
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  5. I. A. Yakushev
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  6. F. M. Dolgushin
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  7. G. G. Aleksandrov
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  8. E. A. Varaksina
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  9. I. V. Taidakov
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  10. E. V. Aleksandrov
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  11. A. A. Sidorov
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  12. I. L. Eremenko
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Correspondence to M. A. Shmelev.

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Translated by E. Yablonskaya

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Shmelev, M.A., Gogoleva, N.V., Makarov, D.A. et al. Synthesis of Coordination Polymers from the Heterometallic Carboxylate Complexes with Chelating N-Donor Ligands. Russ J Coord Chem 46, 1–14 (2020). https://doi.org/10.1134/S1070328420010078

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