Skip to main content
SpringerLink
Log in

Crystal structure, fluorescence spectroscopy, and electrochemical property of two neodymium coordination polymers with phenoxy acids

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Two nine-coordination coordination polymers of neodymium, [Nd2(p-C8H4O4)(o-C8H4O4)2 • 4H2O] n (I), [Nd2(C10H4O8)(C10H2O8) • 2H2O] n (II), have been prepared by hydrothermal reaction of Nd(NO3)3 • 6H2O with terephthalic acid and phthalic acid, or benzenetetracarboxylic anhydride and determined by means of IR, UV, fluorescence, TG-DTA, cyclic voltammetry (CV) and X-ray single-crystal diffraction methods (CIF files CCDC nos. 1006206 (I), 979309 (II)). Yellow-green luminescence could been observed at 391 nm (λex = 305 nm) for complex I and 370 nm (λex = 331 nm) for the complex II. The emission of complexes I and II may be due to the π* → n transition, which may be assigned to the ligand-to-metal charge-transfer bands. Compared with complex II, the complex I exhibits a stronger fluorescence intensity for the different coordinated environment. Cyclic voltammetric measurement of the two compounds reveal that the compounds both have a couple of irreversible redox peak, indicating that the two polymers were both corresponded to the unusual Nd(III)/Nd(V).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ye, J., Wang, Q., Gao, H., et al., Inorg. Chim. Acta, 2012, vol. 384, p. 1.

    Article  CAS  Google Scholar 

  2. Shi, P., Chen, Z., Xiong, G., et al., Cryst. Growth Des., 2012, vol. 12, p. 5203.

    Article  CAS  Google Scholar 

  3. She, J., Gao, C., Cui, K., et al., Struct. Chem., 2008, vol. 19, p. 905.

    Article  CAS  Google Scholar 

  4. Li, X., Wu, X.S., Sun, H.L., et al., Inorg. Chim. Acta, 2009, vol. 362, p. 2837.

    Article  CAS  Google Scholar 

  5. Kusrini, E., Saleh, M.I., Adnan, R., et al., J. Incl. Phen. Macro. Chem., 2012, vol. 74, p. 425.

    Article  CAS  Google Scholar 

  6. Kusrini, E., Saleh, M.I., Yoshioka, N., and Fun, H.K., J. Chem. Crystallogr., 2012, vol. 42, p. 859.

    Article  CAS  Google Scholar 

  7. Souza, A.P., Rodrigues, L.C.V., Brito, H.F., et al., Inorg. Chem. Commun., 2012, vol. 15, p. 97.

    Article  CAS  Google Scholar 

  8. Wong, K.L., Kwok, W.M., Wong, W.T., et al., Angew. Chem. Int. Ed., 2004, vol. 43, p. 4659.

    Article  CAS  Google Scholar 

  9. Matrosov, E.I., Goryunova, I.B., Lysenko, K.A., et al., Russ. J. Inorg. Chem., 2011, vol. 56, p. 539.

    Article  CAS  Google Scholar 

  10. Ye, Q., Wang, X.S., Zhao, H., et al., Tetrahedron, 2005, vol. 16, p. 1595.

    Article  CAS  Google Scholar 

  11. Mondry, A. and Starynowicz, A., Polyhedron, 2000, vol. 19, p. 771.

    Article  CAS  Google Scholar 

  12. Zhang, L.L., Yao, Y.M., Luo, Y.J., et al., Polyhedron, 2000, vol. 19, p. 2243.

    Article  CAS  Google Scholar 

  13. Hu, J.S., Yao, X.Q., Zhang, M.D., et al., Crys. Growth Des., 2012, vol. 12, p. 3426.

    Article  CAS  Google Scholar 

  14. Lin, H.Y., Liu, P., Zhang, J.W., et al., J. Coord. Chem., 2013, vol. 66, p. 612.

    Article  CAS  Google Scholar 

  15. Liu, X.Y., Cen, P.P., Li, H., et al., Inorg. Chem., 2014, vol. 53, p. 8088.

    Article  CAS  Google Scholar 

  16. Liu, X.Y., Cen, P.P., Zhou, H.L., et al., Inorg. Chem. Commun., 2015, vol. 53, p. 11.

    Article  Google Scholar 

  17. Wang, Y.F., Chen, J.Q., and Geng, J.L., Z. Anorg. Allgem. Chem., 2014, vol. 40, p. 2086.

    Article  Google Scholar 

  18. She, J., Li, D., Hou, C., et al., J. Rare Earths, 2011, vol. 29, p. 193.

    Article  CAS  Google Scholar 

  19. Lyszczek, R. and Mazur, L., Central. Eur. J. Chem., 2012, vol. 10, p. 1165.

    CAS  Google Scholar 

  20. Sheldrick, G.M., SHELXS-97, Program for the Solution of Crystal Structure, Gttingen: Univ. of Gttingen, 2008.

    Google Scholar 

  21. Sheldrick, G.M., SHELXS-97, Program for the Refinement of Crystal Structure, Gttingen (Germany): Univ. of Gttingen, 2008.

    Google Scholar 

  22. Li, C.H., Huang, K.L., Chi, Y.N., et al., Inorg. Chem., 2009, vol. 48, p. 2010.

    Article  CAS  Google Scholar 

  23. Wang, J., Lu, X., Li, Z.Y., et al., J. Inorg. Chem., 2011, vol. 27, p. 580.

    Google Scholar 

  24. Khedr, A.M., Gaber, M., and El-Zaher, A., Chin. J. Chem., 2011, vol. 29, p. 1124.

    Article  CAS  Google Scholar 

  25. Nejati, K., Rezvani, Z., and Seyedahmadian, M., Dyes and Pigments, 2009, vol. 83, p. 304.

    Article  CAS  Google Scholar 

  26. Chandler, B.D., Cramb, D.T., and Shimizu, G.K.H., J. Am. Chem. Soc., 2006, vol. 128, p. 10403.

    Article  CAS  Google Scholar 

  27. Yang, L.R., Song, S., Zhang, W., et al., Synth. Met., 2011, vol. 161, p. 647.

    Article  CAS  Google Scholar 

  28. Wang, Z. and Yang, B., Spectrochim. Acta, A, Mol. Biomol. Spectrosc., 2006, vol. 65, p. 946.

    Article  Google Scholar 

  29. Mahata, P., Ramy, K.V., and Natarajan, S., Dalton Trans., 2007, vol. 36, p. 4017.

    Article  Google Scholar 

  30. Qiao, Y., Da, N., Chen, D., et al., Appl.Phys. B: Lasers Opt., 2007, vol. 87, p. 717.

    Article  CAS  Google Scholar 

  31. Wang, J., Li, F.B., Tian, L.H., et al., J. Coord. Chem., 2011, vol. 64, p. 2312.

    Article  CAS  Google Scholar 

  32. Cao, R., Sun, D., Liang, Y., et al., Inorg. Chem., 2002, vol. 41, p. 2087.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Hubei Callaborative Innovation Center for Advanced Organic Chemical Materials, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062, P.R. China

    C. Y. Li, D. M. Cai, J. C. Yin, L. P. Cai, M. Zeng, J. Wang & W. H. Zhu

  2. Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Ministry of Education, Wuhan, 430062, P.R. China

    J. Wang

Authors
  1. C. Y. Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. M. Cai
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. C. Yin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. P. Cai
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. Zeng
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. J. Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. W. H. Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to J. Wang.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, C.Y., Cai, D.M., Yin, J.C. et al. Crystal structure, fluorescence spectroscopy, and electrochemical property of two neodymium coordination polymers with phenoxy acids. Russ J Coord Chem 42, 476–485 (2016). https://doi.org/10.1134/S107032841606004X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107032841606004X

Search

Navigation