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Synthesis, crystal structure, and antibacterial activity of a manganese(III) complex derived from N,N′-3,4-chlorophenylene-bis(5-methylsalicylaldimine)

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Abstract

A new mononuclear manganese(III) complex has been synthesized from the Schiff base compound N,N′-3,4-chlorophenylene-bis(5-methylsalicylaldimine) and manganese perchlorate in the presence of sodium azide. The complex has been characterized by physico-chemical and spectroscopic methods, as well as single crystal X-ray determination (CIF file CCDC no. 1054335). The Mn atom in the complex is six-coordinate by two nitrogen and two oxygen atoms of the Schiff base ligand, one nitrogen atom of an azide ligand, and one oxygen atom of a methanol ligand. Crystal structure of the complex is stabilized by hydrogen bonds and π···π interactions. The complex and the Schiff base compound were assayed for antibacterial activities against three Gram-positive bacterial strains (B. subtilis, S. aureus, and St. faecalis) and three Gram-negative bacterial strains (E. coli, P. aeruginosa, and E. cloacae) by MTT method. As a result, the complex showed effective antimicrobial activity against the microorganisms tested.

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Authors and Affiliations

  1. Modern Medical Research Center, Third Affiliated Hospital of Soochow University, Changzhou, 213003, P.R. China

    L. Xue, D. N. Deng, Y. Xu & Q. Wang

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  1. L. Xue
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  2. D. N. Deng
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  3. Y. Xu
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  4. Q. Wang
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Correspondence to Q. Wang.

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Xue, L., Deng, D.N., Xu, Y. et al. Synthesis, crystal structure, and antibacterial activity of a manganese(III) complex derived from N,N′-3,4-chlorophenylene-bis(5-methylsalicylaldimine). Russ J Coord Chem 41, 772–776 (2015). https://doi.org/10.1134/S107032841511010X

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  • DOI: https://doi.org/10.1134/S107032841511010X

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