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State of rhodium(III) in sulfuric acid solutions

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Abstract

The formation of rhodium(III) sulfate complexes under moderately rigorous temperature conditions was studied by 103Rh and 17O NMR spectroscopy. The complexes [Rh2(μ-SO4)2(H2O)8]2+, [Rh2(*μ-SO4)(H2O)8]4+, and [Rh3(μ-SO4)3(μ-OH)(H2O)10]2+ were found to be the most stable species in aged solutions.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    A. V. Belyaev & S. N. Shagabutdinova

  2. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

    M. A. Fedotov

Authors
  1. A. V. Belyaev
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  2. M. A. Fedotov
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  3. S. N. Shagabutdinova
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Original Russian Text © A.V. Belyaev, M.A. Fedotov, S.N. Shagabutdinova, 2007, published in Koordinatsionnaya Khimiya, 2007, Vol. 33, No. 2, pp. 141–145.

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Belyaev, A.V., Fedotov, M.A. & Shagabutdinova, S.N. State of rhodium(III) in sulfuric acid solutions. Russ J Coord Chem 33, 136–139 (2007). https://doi.org/10.1134/S107032840702011X

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  • DOI: https://doi.org/10.1134/S107032840702011X

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