Abstract
Possible variants of the Mott-Hubbard phase transitions at high pressure in systems with spin crossovers are considered. Owing to the universal character of the dependence of the effective Hubbard parameter U eff(d n) on the average number of d electrons, which is determined by the presence of spin crossovers, cascades of insulator-metal-insulator phase transitions in systems with d 3, d 6, and d 8 configurations become possible. Moreover, the systems with d 6 configuration can exhibit transitions from a metal in the absence of external pressure to an insulator at high pressure.
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Original Russian Text © S.G. Ovchinnikov, 2013, published in Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2013, Vol. 143, No. 1, pp. 141–146.
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Ovchinnikov, S.G. Analysis of the sequence of insulator-metal phase transitions at high pressure in systems with spin crossovers. J. Exp. Theor. Phys. 116, 123–127 (2013). https://doi.org/10.1134/S1063776113010111
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DOI: https://doi.org/10.1134/S1063776113010111