Abstract
The growth of organic single crystals of naphthalene (C10H8) and anthracene (С14H10) at the liquid‒air interface from a mixture of solvents has been investigated. The growth technique used in the study makes it possible to obtain single-crystal sheets up to 10 mm in size for 24 h. The surface morphology and structure of the crystals have been analyzed by optical microscopy and X-ray diffraction. C10H8 and С14H10 single crystals grow coplanarly along the (001) plane. A thermodynamic model of the flat-crystal nucleus formation at the liquid‒air interface, based on the analysis of the change in the free Gibbs energy, is considered.
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References
J. Zaumseil and H. Sirringhaus, Chem. Rev. 107, 1296 (2007).
I. Kymissis, Organic Field Effect Transistors (Springer, 2009).
S. Z. Bisri, T. Takenobu, Y. Yomogida, et al., Adv. Funct. Mater. 19 (11),1728 2009.
H.-H. Fang, R. Ding, S.-Y. Lu, et al., J. Mater. Chem. 22, 24139 (2012).
Y. Inada, T. Yamao, M. Inada, et al., Synth. Met. 161 (17–18), 1869 (2011).
H. Shang, H. Wang, N. Gao, et al., Cryst. Eng. Commun. 14, 869 (2012).
V. A. Postnikov, Y. I. Odarchenko, A. V. Iovlev, et al., Cryst. Growth Des. 14, 1726 (2014).
V. A. Postnikov, Kondens. Sredy Mezhfaznye Granitsy 15 (2),74 2013.
V. Ya. Rabinovich and Z. Ya. Khavin, Brief Chemical Handbook (Khimiya, Leningrad, 1991) [in Russian].
F. P. A. Fabbiani, D. R. Allan, S. Parsons, and C. R. Pulham, Acta Crystallogr. B 62, 826 (2006).
C. Pratt Brock and J. D. Dunitz, Acta Crystallogr. B 46, 795 (1990).
O. Ya. Neiland, Organic Chemistry (Vyssh. shkola, Moscow, 1990) [in Russian].
A. Adamson, Physical Chemistry of Surfaces (Wiley, New York, 1967; Mir, Moscow, 1979).
Modern Crystallography, Vol. 3: Crystal Growth, Ed. by B. K. Vainshtein, A. A. Chernov, and L. A. Shuvalov (Nauka, Moscow, 1979) Vol. 3, p. 55 [in Russian].
P. A. Rebinder and E. D. Shchukin, Usp. Fiz. Nauk 108 (1),19 1972.
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Original Russian Text © V.A. Postnikov, S.V. Chertopalov, 2015, published in Kristallografiya, 2015, Vol. 60, No. 4, pp. 651–658.
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Postnikov, V.A., Chertopalov, S.V. Growth of large naphthalene and anthracene single-crystal sheets at the liquid–air interface. Crystallogr. Rep. 60, 594–600 (2015). https://doi.org/10.1134/S106377451503013X
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DOI: https://doi.org/10.1134/S106377451503013X