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Synthesis and crystal structure of Na3(H3O)[UO2(SeO3)2]2· H2O

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Abstract

Single crystals of the compound Na3(H3O)[UO2(SeO3)2]2 · H2O (I) have been synthesized, and their structure has been investigated using X-ray diffraction. Compound I crystallizes in the triclinic system with the unit cell parameters a = 9.543(6)Å, b = 9.602(7)Å, c = 11.742(8)Å, α = 66.693(16)°, β = 84.10(2)°, γ = 63.686(14)°, space group P \( \bar 1 \), Z = 2, and R = 0.0734. The uranium-containing structural units of the crystals are [UO2(SeO3)2]2− chains, which belong to the crystal-chemical group AB 2 B 11 (A = UO 2+2 , B 2 = SeO 2−3 , B 11 = SeO 2−3 ) of the uranyl complexes. The structures of the compounds containing the [UO2(SeO3)2]2− anionic complexes are compared.

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Authors and Affiliations

  1. Samara State University, ul. Akademika Pavlova 1, Samara, 443011, Russia

    L. B. Serezhkina, A. V. Marukhnov, D. V. Pushkin & V. N. Serezhkin

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    A. V. Vologzhanina

Authors
  1. L. B. Serezhkina
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  2. A. V. Vologzhanina
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  3. A. V. Marukhnov
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  4. D. V. Pushkin
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  5. V. N. Serezhkin
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Correspondence to L. B. Serezhkina.

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Dedicated to the memory of G.B. Bokiĭ on the occasion of his 100th birthday

Original Russian Text © L.B. Serezhkina, A.V. Vologzhanina, A.V. Marukhnov, D.V. Pushkin, V.N. Serezhkin, 2009, published in Kristallografiya, 2009, Vol. 54, No. 5, pp. 898–903.

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Serezhkina, L.B., Vologzhanina, A.V., Marukhnov, A.V. et al. Synthesis and crystal structure of Na3(H3O)[UO2(SeO3)2]2· H2O. Crystallogr. Rep. 54, 852–857 (2009). https://doi.org/10.1134/S1063774509050186

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  • DOI: https://doi.org/10.1134/S1063774509050186

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