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Comparison of the Efficiencies of Carbon Sorbents for the Preconcentration of Highly Volatile Organic Substances from Wet Gas Atmospheres for the Subsequent Gas-Chromatographic Determination

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Abstract

The efficiencies of various carbon sorbents in the preconcentration of volatile organic substances from a stream of humid air for their subsequent gas-chromatographic determination are compared. A hybrid procedure for rapid analysis including the sorption preconcentration of analytes on a selected carbon–fluoroplastic composite sorbent and their one-stage thermal desorption in the injector of a chromatograph with a capillary column and a flame-ionization detector is proposed. This procedure makes it possible to determine lower alcohols and ketones in air saturated with water vapor for 5–10 min with determination limits at a level of several μg/m3.

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REFERENCES

  1. Krylov, V.A., Mosyagin, P.V., Mikhirev, D.A., Eremin, S.A., and Krylov, A.V., Russ. Chem. Rev., 2010, vol. 79, no. 6, p. 531.

    Article  CAS  Google Scholar 

  2. Demeestere, K., Dewulf, J., De Witte, B., and Van Langenhove, H., J. Chromatogr. A, 2007, vol. 1153, p. 130.

    Article  CAS  PubMed  Google Scholar 

  3. Shirasu, M. and Touhara, K., J. Biochem., 2011, vol. 150, no. 3, p. 257.

    Article  CAS  PubMed  Google Scholar 

  4. Vaks, V.L., Domracheva, E.G., Sobakinskaya, E.A., and Chernyaeva, M.B., Phys.—Usp., 2014, vol. 57, p. 684.

    Article  CAS  Google Scholar 

  5. Snow, N.H. and Slack, G.C., TrAC, Trends Anal. Chem., 2002, vol. 21, p. 608.

    Article  CAS  Google Scholar 

  6. Chary, N.S. and Fernandez-Alba, A.R., TrAC, Trends Anal. Chem., 2012, vol. 32, p. 60.

    Article  CAS  Google Scholar 

  7. Rodinkov, O.V., Bugaichenko, A.S., Moskvin, L.N., Gorbacheva, A.R., and Vagner, E.A., J. Anal. Chem., 2018, vol. 73, no. 5, p. 432.

    Article  CAS  Google Scholar 

  8. GOST (State Standard) R ISO 16017-1-2007: Indoor, Ambient and Workplace Air. Sampling and Analysis of Volatile Organic Compounds by Sorbent Tube/Thermal Desorption/Capillary Gas Chromatography. Part 1: Pumped Sampling, Moscow: Standartinform, 2008.

  9. Berezkin, V.G. and Nikitina, N.S., Russ. Chem. Rev., 1971. vol. 40, no. 5, p. 456.

    Article  Google Scholar 

  10. Rodinkov, O.V. and Moskvin, L.N., J. Anal. Chem., 2012, vol. 67, no. 10, p. 814.

    Article  CAS  Google Scholar 

  11. Rodinkov, O.V., Bugaichenko, A.S., and Vlasov, A.Yu., Talanta, 2014, vol. 119, p. 407.

    Article  CAS  PubMed  Google Scholar 

  12. Postnov, V.N., Rodinkov, O.V., Moskvin, L.N., Novikov, A.G., Bugaichenko, A.S., and Krokhina, O.A., Russ. Chem. Rev., 2016, vol. 85, no. 2, p. 115.

    Article  CAS  Google Scholar 

  13. Plachenov, T.G. and Kolosentsev, S.D., Porometriya (Porosity Measurement), Leningrad: Khimiya, 1988.

    Google Scholar 

  14. ISO 15901-2:2006: Pore Size Distribution and Porosity of Solid Materials by Mercury Porosimetry and Gas Adsorption. Part 2: Analysis of Mesopores and Macropores by Gas Adsorption, International Organization for Standardization, 2006. http://www.iso.org/standard/39386.html. Accessed May 10, 2018.

  15. ISO 15901-3:2007: Pore Size Distribution and Porosity of Solid Materials by Mercury Porosimetry and Gas Adsorption. Part 3: Analysis of Micropores by Gas Adsorption, International Organization for Standardization, 2007. http://www.iso.org/standard/40364.html. Accessed May 10, 2018.

  16. Platonov, I.A., Rodinkov, O.V., Gorbacheva, A.R., Moskvin, L.N., and Kolesnichenko, I.N., J. Anal. Chem., 2018, vol. 73, no. 2, p. 109.

    Article  CAS  Google Scholar 

  17. Ioffe, B.V. and Vitenberg, A.G., Headspace Analysis and Related Methods in Gas Chromatography, New York: Wiley, 1984, p. 22.

    Google Scholar 

  18. Drugov, Yu.S., Konopel’ko, L.A., and Popov, O.G., Kontrol’ zagryaznenii vozdukha zhilykh pomeshchenii, ofisov, administrativnykh i ofisnykh pomeshchenii (Air Pollution Control of Residential Rooms, Offices, Administrative, and Office Rooms), St. Petersburg: Nauka, 2013, p. 76.

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Funding

This work was supported by the Russian Science Foundation (grant no. 16-13-10117) and performed with the use of the equipment of the Chemistry Resource Education Center at the St. Petersburg State University.

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Authors and Affiliations

  1. Institute of Chemistry, St. Petersburg State University, 198504, Petrodvorets, St. Petersburg, Russia

    O. V. Rodinkov, E. A. Vagner, A. S. Bugaichenko & L. N. Moskvin

Authors
  1. O. V. Rodinkov
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  2. E. A. Vagner
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  3. A. S. Bugaichenko
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  4. L. N. Moskvin
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Corresponding author

Correspondence to O. V. Rodinkov.

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Translated by V. Makhlyarchuk

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Rodinkov, O.V., Vagner, E.A., Bugaichenko, A.S. et al. Comparison of the Efficiencies of Carbon Sorbents for the Preconcentration of Highly Volatile Organic Substances from Wet Gas Atmospheres for the Subsequent Gas-Chromatographic Determination. J Anal Chem 74, 877–882 (2019). https://doi.org/10.1134/S1061934819090089

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  • DOI: https://doi.org/10.1134/S1061934819090089

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