Abstract
The chromatographic properties of poly(1-trimethylsilyl-1-propyne) (PTMSP) and poly(1-phenyl-1-propyne) (PPP) were studied by gas chromatography using packed columns. The selectivity and efficiency of columns packed with PTMSP and PPP were compared to the data obtained for columns with other known adsorbents and stationary phases. The McReynolds and Rohrschneider constants, on the basis of which the polarity of the new phases was evaluated, were calculated. The results of the investigation of chromatographic properties allow PTMSP to be brought in line with the polymeric adsorbents Porapak Q, Porapak QS, and Chromosorb 106, while PPP, with the methyphenylsilicon phases SE-52 and OV-3.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Masuda, T., Isobe, E., and Higashimura, T., Macromolecules, 1985, vol. 18, no. 5, p. 841.
Masuda, T., Takahashi, T., and Higashimura, T., Macromolecules, 1985, vol. 18, no. 3, p. 311.
Berezkin, V.G., Korolev, A.A., and Khotimskii, V.S., Dokl. Akad. Nauk, 2000, vol. 370, no. 3, p. 200 [Dokl. (Engl. Transl.), vol. 370, nos. 1–3, p. 1].
Berezkin, V.G., Popova, T.P., Shiryaeva, V.E, Kozlov, S.P., and Vlasenko, E.V., Zavod. Lab. Diagn. Mater., 2003, vol. 69, no. 10, p. 3.
Berezkin, V.G., Popova, T.P., and Shiryaeva, V.E., Izv. Ross. Akad. Nauk, Ser.: Khim., 2001, no. 2, p. 225.
Berezkin, V.G, Popova, T.P., Shiryaeva, V.E., Korolev, A.A., and Malyukova, I.V., Izv. Ross. Akad. Nauk, Ser.: Khim., 2002, no. 5, p. 765.
Berezkin, V.G., Mukhina, V.P., Korolev, A.A., Fatkullina, A.F., and Seroshtan, V.A., Zavod. Lab. Diagn. Mater., 2004, vol. 70, no. 5, p. 9.
Krylov, V.A., Berezkin, V.G., Chernova, O.Yu., Saltanskii, Yu.M., and Korolev, A.A., Zhurn. Anal. Khim., 2003, vol. 58, no. 4, p. 421 [J. Anal. Chem. (Engl. Transl.), vol. 58, no. 4, p. 372].
Yakovleva, E.Yu., Yakushina, I.A., and Skrypnik, O.V., Kataliz v Promyshl., 2006, no. 6, p. 28.
Morliere, N., Vallieres, C., Perrin, L., and Roizard, D., J. Membrane Sci., 2006, vol. 270, p. 123.
Starannikova, L., Khodzhaeva, V., and Yampolskii, Y., J. Membrane Sci., 2004, vol. 244, p. 183.
Berezkin, V.G., Korolev, A.A., Malyukova, I.V., Mardanov, R.G., Khotimskii, V.S., and Yampol’skii, Yu.P., Izv. Ross. Akad. Nauk, Ser.: Khim., 2001, no. 7, p. 1171.
Yakovleva, E.Yu., Belotserkovskaya, V.Yu., Fadeeva, V.P., Litvak, G.S., Paukshtis, E.A., and Babushkin, D.E., Zhurn. Fiz. Khim., 2009, vol. 83, no. 5, p. 972 [Russ. J. Phys. Chem. (Engl. Transl.), vol. 83, no. 5, p. 849].
Madkour Tarek, M., Polymer Data Handbook, New York: Oxford University Press, 1999.
Supina, V., Nasadochnye kolonki v gazovoi khromatografii (Packed Columns in Gas Chromatography), Moscow: Mir, 1977.
Sakodynskii, K.I. and Panina, L.I., Polimernye sorbenty dlya molekulyarnoi khromatografii (Polymeric Adsorbents for Molecular Chromatography), Moscow: Nauka, 1977.
Gol’dbert, K.A. and Vigdergaus, M.S., Vvedenie v gazovuyu khromatografiyu (Introduction to Gas Chromatography), Moscow: Khimiya, 1990.
Castello, G. and D’amato, G., J. Chromatogr., 1986, vol. 366, p. 51.
Author information
Authors and Affiliations
Additional information
Original Russian Text © E.Yu. Yakovleva, V.Yu. Belotserkovskaya, 2010, published in Zhurnal Analiticheskoi Khimii, 2010, Vol. 65, No. 10, pp. 1039–1045.
Rights and permissions
About this article
Cite this article
Yakovleva, E.Y., Belotserkovskaya, V.Y. Chromatographic properties and polarity evaluation of poly(1-trimethylsilyl-1-propyne) and poly(1-phenyl-1-propyne). J Anal Chem 65, 1014–1020 (2010). https://doi.org/10.1134/S1061934810100059
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934810100059