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Removal of Congo red from aqueous solutions by neem saw dust carbon

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Abstract

Neem sawdust was used to develop an effective carbon adsorbent. This adsorbent was used for the removal of Congo Red (CR) from aqueous solution. The data suggest that the pH of aqueous solutions influences CR removal due to the decrease of removal efficiency with increasing pH. An optimal pH < 3 for the adsorption of CR onto neem sawdust carbon (NSDC) was determined. The experimental data were analysed by the Langmuir, Freundlich, Redlich-Peterson, Toth, Temkin, Sips and Dubinin-Radushkevich models of adsorption. Three simplified kinetic models based on pseudo-first-order, pseudo-second-order and intraparticle diffusion equations were used to describe the adsorption process. It was shown that the adsorption of CR could be described by the pseudo-second-order equation, suggesting that the adsorption occurs as a chemisorption process. The results indicate that the NSDC can be used as a low cost adsorbent alternative to commercial activated carbon for the removal of dyes from wastewaters.

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References

  1. Chiou, M.S., Ho, P., Ho, Y., and Li, H.Y., Dyes Pigm., 2004, vol. 60, p. 69.

    Article  CAS  Google Scholar 

  2. Gong, R., Ding, Y., Li, M., et al. Dyes Pigm., 2005, vol. 64, p. 187.

    Article  CAS  Google Scholar 

  3. Seshadri, S., Bishop, P.L., and Agha, A.M., Waste Manag., 1994, vol. 15, p. 127.

    Article  Google Scholar 

  4. Neamtu, M., Yediler, A., Siminiceanu, I., et al., Dyes Pigm., 2004, vol. 60, p. 61.

    Article  CAS  Google Scholar 

  5. Gupta, G.S., Prasad, G., and Singh, V.N., Water Res., 1990, vol. 24, p. 45.

    Article  CAS  Google Scholar 

  6. Halliday, P.J. and Beszedits, S., Can. Text. J., 1986, vol. 103, p. 78.

    Google Scholar 

  7. Patil, S.S. and Shinde, V.M., Environ. Sci. Technol., 1988, vol. 22, p. 1160.

    Article  CAS  Google Scholar 

  8. Wahi, R.K., Yu, W.W., Liu, Y.P., et al., J. Mol. Catal., A: Chem., 2005, vol. 242, p. 48.

    Article  CAS  Google Scholar 

  9. Rao, V.V.B. and Rao, S.R.M., Chem. Eng. J., 2006, vol. 116, p. 13.

    Article  Google Scholar 

  10. Rao, K.C.L.N. and Ashutosh, K.K., Indian J. Chem. Technol., 1994, vol. 1, p. 13.

    CAS  Google Scholar 

  11. Pelekani, C. and Snoeyink, V.L., Carbon, 2001, vol. 39, p. 25.

    Article  CAS  Google Scholar 

  12. Lorenc-Grabowska, E. and Gryglewicz, G., Dyes Pigm., 2007, vol. 74, p. 34.

    Article  CAS  Google Scholar 

  13. McKay, G., Use of Adsorbents for the Removal of Pollutants from Wastewaters, Boca Raton: CRC, 1996.

    Google Scholar 

  14. Gharaibeh, S.H., Moore, S.V., and Buck, A., J. Chem. Technol. Biotechnol., 1998, vol. 71, p. 291.

    Article  CAS  Google Scholar 

  15. Pala, A. and Tokat, E., Water Res., 2002, vol. 36, p. 2920.

    Article  CAS  Google Scholar 

  16. Karthikeyan, J., in Pollution Management in Industries, Trivedy, R.K., Ed., Karad, India: Environmental, 1988, p. 189.

    Google Scholar 

  17. Mohan, S.V. and Karthikeyan, J., Environ. Pollut., 1997, vol. 97, p. 183.

    Article  CAS  Google Scholar 

  18. Sankar, M., Sekaran, G., Sadulla, S., and Ramasami, T., J. Chem. Technol. Biotechnol., 1999, vol. 74, p. 337.

    Article  CAS  Google Scholar 

  19. Nassar, M.M., Abstracts of Papers, Meet. on Chemical Engineering and Biotechnology, ACHEMA-94, Frankfurt, 1994.

  20. Nassar, M.M. and El-Geundi, M.S., J. Chem. Technol. Biotechnol., 1991, vol. 50, p. 257.

    Article  CAS  Google Scholar 

  21. Asfour, H.M., Fadali, O.A., Nassar, M.M., and El-Geundi, M.S., J. Chem. Technol. Biotechnol., 1985, vol. 35A, p. 28.

    CAS  Google Scholar 

  22. El-Geundi, M.S., Water Res., 1991, vol. 25, p. 271.

    Article  CAS  Google Scholar 

  23. McKay, G. and Allen, S.J., J. Separ. Process. Technol., 1983, vol. 4, p. 1.

    CAS  Google Scholar 

  24. Puri, B.R., Chemistry and Physics of Carbon, New York: Marcel Dekker, 1970.

    Google Scholar 

  25. Namasivayam, C. and Kavitha, D., Dyes Pigm., 2002, vol. 54, p. 47.

    Article  CAS  Google Scholar 

  26. Namasivayam, C., Radhika, R., and Suba, S., Waste Manag., 2001, vol. 21, p. 381.

    Article  CAS  Google Scholar 

  27. Ho, Y.S. and Chiang, C.C., Adsorption, 2001, vol. 7, p. 139.

    Article  CAS  Google Scholar 

  28. Galiatsatou, P., Metaxas, M., and Kasselouri-Rigopoulou, V., J. Hazard. Mater., 2002, vol. 91, p. 187.

    Article  CAS  Google Scholar 

  29. Mattson, J.S. and Mark, H.B., Jr., Activated Carbon: Surface Chemistry and Adsorption from Solution, New York: Marcel Dekker, 1971.

    Google Scholar 

  30. Wong, Y. and Yu, J., Water Res., 1999, vol. 33, p. 3512.

    Article  CAS  Google Scholar 

  31. Malik, P.K., Dyes Pigm., 2003, vol. 56, p. 239.

    Article  CAS  Google Scholar 

  32. Langmuir, I., J. Am. Chem. Soc., 1918, vol. 40, p. 1361.

    Article  CAS  Google Scholar 

  33. Freundlich, H.M.F., J. Phys. Chem., 1906, vol. 57, p. 385.

    CAS  Google Scholar 

  34. Redlich, O. and Peterson, D.L., J. Phys. Chem., 1959, vol. 63, p. 1024.

    Article  CAS  Google Scholar 

  35. Toth, J., Acta Chim. Acad. Sci. Hung., 1971, vol. 69, p. 311.

    CAS  Google Scholar 

  36. Temkin, M.J. and Pyzhev, V., Acta Physicochim. URSS, 1940, vol. 12, p. 217.

    Google Scholar 

  37. Volesky, B., Hydrometallurgy, 2003, vol. 71, p. 179.

    Article  CAS  Google Scholar 

  38. Dubinin, M.M. and Radushkevich, L.V., Chem. Zent., 1947, vol. 1, p. 875.

    Google Scholar 

  39. Lagergren, S., Kungliga Svenska Vetensk Handl., 1898, vol. 24, no. 4, p. 1.

    Google Scholar 

  40. Ho, Y.S. and McKay, G., Process. Biochem., 1999, vol. 34, no. 5, p. 451.

    Article  CAS  Google Scholar 

  41. Baskaralingam, P., Pulikesi, M., Elango, D., et al., J. Hazard. Mater., 2006, vol. 128, p. 138.

    Article  CAS  Google Scholar 

  42. Ozcan, A.S., Erdem, B., and Ozcan, A., Colloids Surf., A, 2005, vol. 266, p. 73.

    Article  Google Scholar 

  43. Weber, W.J. and Morris, J.C., J. Sanit. Eng., Div. Am. Soc. Civ. Eng., 1963, vol. 89, p. 31.

    Google Scholar 

  44. Annadurai, G., Juang, R.S., and Lee, D.J., J. Hazard. Mater., 2002, vol. 92, p. 263.

    Article  CAS  Google Scholar 

  45. Wu, F.C., Tseng, R.L., and Juang, R.S., Environ. Technol., 2001, vol. 22, p. 205.

    Article  CAS  Google Scholar 

  46. Singh, B. and Rawat, N.S., J. Chem. Technol. Biotechnol., 1994, vol. 61, p. 57.

    Article  CAS  Google Scholar 

  47. Gupta, G.S., Prasad, G., and Singh, V.N., Water Res., 1990, vol. 24, p. 45.

    Article  CAS  Google Scholar 

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Correspondence to P. Senthil Kumar.

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Senthil Kumar, P. Removal of Congo red from aqueous solutions by neem saw dust carbon. Colloid J 72, 703–709 (2010). https://doi.org/10.1134/S1061933X10050182

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