Skip to main content
SpringerLink
Log in

Formation of liquid-crystalline-type structures in poly(paraamides)

  • Structure and Properties
  • Published:
Polymer Science, Series A Aims and scope Submit manuscript

Abstract

It is shown that the sorption method makes it possible to quantitatively estimate the presence of ordered structures in the supramolecular structure of partially crystalline and liquid-crystalline paraamide polymers. Using 1H NMR spectroscopy and the sorption method, the growth of liquid-crystalline type structures during spinning and thermal treatment of the poly(paraamide) fiber is analyzed. A comparison of the 1H NMR spectra of the as-spun and heat-treated fibers at low temperatures (110–210 K) in a rigid lattice reveals that “loose” disordered microregions occur in the fiber before thermal treatment. Thermal treatment results in the “healing” of structural defects and leads to the appearance of liquid-crystalline-type structures owing to the large-scale quasi-segmental motion at a high temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. M. Pakhomov, V. P. Galitsyn, S. D. Khizhnyak, and A. E. Chmel’, High strength and High-Modulus Polymer Fibers (Tverskoi Gos. Univ., Tver, 2012) [in Russian].

    Google Scholar 

  2. S. P. Papkov and V. K. Kulichikhin, Liquid-Crystalline State of Polymers (Khimiya, Moscow, 1977) [in Russian].

    Google Scholar 

  3. A. V. Volokhina, Yu. K. Godovskii, and G. I. Kudryavtsev, Liquid-Crystalline Polymers, Ed. by N. A. Plate (Khimiya, Moscow, 1988) [in Russian].

  4. A. A. Tager, Physics and Chemistry of Polymers (Nauchnyi mir, Moscow, 2007) [in Russian].

    Google Scholar 

  5. S. P. Papkov and E. Z. Fainberg, Interaction of Cellulose and Cellulose-Based Materials with Water (Khimiya, Moscow, 1976) [in Russian].

    Google Scholar 

  6. A. E. Chalykh, Water Diffusion in Polymer Systems (Khimiya, Moscow, 1987) [in Russian].

    Google Scholar 

  7. L. Penn, Appl. Polym. Sci. 23, 59 (1979).

    Article  CAS  Google Scholar 

  8. M. M. Iovleva, L. Ya. Konovalova, G. S. Negodyaev, A. N. Sokira, L. V. Avrorova, A. V. Volokhina, and S. P. Papkov, Vysokomol. Soedin., Ser. B 25 (10), 776 (1983).

    Google Scholar 

  9. M. M. Iovleva, L. Ya. Konovalova, L. I. Drozd, S. I. Banduryan, V. A. Platonov, G. S. Negodyaeva, N. N. Machalaba, and G. A. Budnitskii, Fibre Chem. 33 (1), 25 (2001).

    Article  CAS  Google Scholar 

  10. M. M. Iovleva, Polym. Sci., Ser. A 50 (7), 767 (2008).

    Article  Google Scholar 

  11. I. Ya. Slonim and A. N. Lyubimov, NMR in Polymers (Khimiya, Moscow, 1966) [in Russian].

    Google Scholar 

  12. I. I. Perepechko, Introduction to Polymer Physics (Khimiya, Moscow, 1978) [in Russian].

    Google Scholar 

  13. E. A. Egorov and V. V. Zhizhenkov, J. Polym. Sci., Polym. Phys. Ed. 20 (7), 1089 (1982).

    Article  CAS  Google Scholar 

  14. D. W. Van Krevelen, Properties of Polymers (Elsevier, Amsterdam, 1990).

    Google Scholar 

  15. E. Z. Fainberg and N. V. Mikhailov, Khim. Volokna, No. 3, 43 (1967).

    Google Scholar 

  16. S. F. Grebennikov and Yu. A. El’tekov, Sorption in Polymer Systems (St. Peterburgskii Gos. Univ. Tekhnol. Diz., St. Petersburg, 2014) [in Russian].

    Google Scholar 

  17. E. R. Andrew, Nuclear Magnetic Resonance (Univ. Press, Cambridge, 1957).

    Google Scholar 

  18. E. A. Egorov, M. N. Shuster, V. V. Zhizhenkov, and I. P. Dobrovol’skaya, Vysokomol. Soedin., Ser. A 38 (2), 246 (1996).

    CAS  Google Scholar 

  19. E. A. Egorov and V. V. Zhizhenkov, Polym. Sci., Ser. A 44 (7), 689 (2002).

    Google Scholar 

  20. E. A. Egorov, V. V. Zhizhenkov, I. A. Gorshkova, and A. V. Savitskii, Polym. Sci., Ser. A 46 (8), 790 (2004).

    Google Scholar 

  21. E. A. Egorov, V. V. Zhizhenkov, I. A. Gorshkova, and A. V. Savitsky, Polymer 40 (13), 3891 (1999).

    Article  CAS  Google Scholar 

  22. A. V. Savitskii, E. A. Egorov, V. V. Zhizhenkov, and I. A. Gorshkova, in Physics and Chemistry of Polymers, No. 15, 63 (2009).

    Google Scholar 

  23. E. A. Egorov and V. V. Zhizhenkov, Polym. Sci., Ser. B 46 (11), 334 (2004).

    Google Scholar 

  24. E. A. Egorov and V. V. Zhizhenkov, Phys. Solid State 47 (5), 914 (2005).

    Article  Google Scholar 

  25. A. Biswas and J. Blackwell, Macromolecules 21 (11), 3146 (1988).

    Article  CAS  Google Scholar 

  26. A. E. Zavadskii, I. M. Zakharova, and Z. N. Zhukova, Fibre Chem. 30 (1), 6 (1998).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ioffe Physical-Technical Institute, Russian Academy of Sciences, Politekhnicheskaya ul. 26, St. Petersburg, 194021, Russia

    V. V. Zhizhenkov & N. G. Kvachadze

  2. State University of Technology and Design, Bol’shaya Morskaya ul. 18, St. Petersburg, 191186, Russia

    S. F. Grebennikov & K. N. Busygin

  3. Volga State University of Technology, pl. Lenina 3, Yoshkar-Ola, 424000, Mari El Republic, Russia

    T. V. Smotrina

  4. Кazan National Research Technological University, ul. Karla Marksa 68, Кazan, 420015, Russia

    V. A. Smotrin

Authors
  1. V. V. Zhizhenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. F. Grebennikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. N. Busygin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. G. Kvachadze
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. T. V. Smotrina
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. A. Smotrin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to K. N. Busygin.

Additional information

Original Russian Text © V.V. Zhizhenkov, S.F. Grebennikov, K.N. Busygin, N.G. Kvachadze, T.V. Smotrina, V.A. Smotrin, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya A, 2017, Vol. 59, No. 2, pp. 156–164.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhizhenkov, V.V., Grebennikov, S.F., Busygin, K.N. et al. Formation of liquid-crystalline-type structures in poly(paraamides). Polym. Sci. Ser. A 59, 198–205 (2017). https://doi.org/10.1134/S0965545X17020110

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965545X17020110

Search

Navigation