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A Comparative Study of the Transport Properties of Homogeneous and Heterogeneous Cation-Exchange Membranes Doped with Zirconia Modified with Phosphoric Acid Groups

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Abstract

Composite materials based on MF-4SK membranes (Plastpolimer, Russia), a membrane foil (Mega, Czech Republic), and phosphate-modified zirconia been synthesized; the transport properties of the composites in the proton and potassium forms have been studied. It has been found that the degree of doping of the heterogeneous membranes can be significantly higher than that of the homogeneous samples. It has been shown that the surface modification of zirconia with phosphate groups results in increase in the conductivity (from 0.0029 to 0.011 S/cm) and selectivity of transport processes improvement (from 0.068 to 0.009) in the membrane foil. Differences in the observed values of conductivity and mutual diffusion coefficient of the membranes in the hydrogen and potassium forms have been discussed taking into account the possible ion transport mechanisms.

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REFERENCES

  1. R. W. Baker, Membrane Technology and Applications, 2nd Ed. (Wiley, Chichester, 2004).

    Book  Google Scholar 

  2. B. Kattouf, Y. Ein-Eli, A. Siegmann, and G. L. Frey, J. Mater. Chem. C 1, 151 (2013).

    Article  CAS  Google Scholar 

  3. A. Kusoglu and A. Z. Weber, Chem. Rev. 117, 987 (2017).

    Article  CAS  PubMed  Google Scholar 

  4. E. Bakangura, L. Wu, L. Ge, et al., Prog. Polym. Sci. 57, 103 (2016).

    Article  CAS  Google Scholar 

  5. A. B. Yaroslavtsev, Nanotechnol. Russ. 7, 437 (2012).

    Article  Google Scholar 

  6. D. J. Kim, M. JaeJo, and S. YongNam, J. Ind. Eng. Chem. 21, 36 (2015).

    Article  CAS  Google Scholar 

  7. D. J. Jones and J. Roziere, Handbook of Fuel Cells: Fundamentals, Technology and Applications, vol. 3: Fuel Cell Technology and Applications, Ed. by W. Vielstich, A. Lamm, and H. A. Gasteiger (Wiley, Hoboken, 2003), p. 447.

  8. M. Amjadi, S. Rowshanzamir, S. J. Peighambardoust, and S. Sedghi, J. Power Sources 210, 350 (2012).

    Article  CAS  Google Scholar 

  9. J. Chabé, M. Bardet, and G. Gébel, Solid State Ionics 229, 20 (2012).

    Article  CAS  Google Scholar 

  10. A. Mahreni, A. B. Mohamad, A. A. H. Kadhum, et al., J. Membr. Sci. 327, 32 (2009).

    Article  CAS  Google Scholar 

  11. L. G. Boutsika, A. Enotiadis, I. Nicotera, et al., Int. J. Hydrogen Energy 41, 22406 (2016).

    Article  CAS  Google Scholar 

  12. E. Yu. Voropaeva, E. A. Sanginov, V. I. Volkov, et al., Russ. J. Inorg. Chem. 53, 1536 (2008).

    Article  Google Scholar 

  13. J. Pan, H. Zhang, W. Chen, and M. Pan, Int. J. Hydrogen Energy 35, 2796 (2010).

    Article  CAS  Google Scholar 

  14. M. Taghizadeh and M. Vatanparast, J. Colloid Interface Sci. 483, 1 (2016).

    Article  CAS  PubMed  Google Scholar 

  15. G. A. Giffin, M. Piga, S. Lavina, et al., J. Power Sources 198, 66 (2012).

    Article  CAS  Google Scholar 

  16. Y. Zhai, H. Zhang, J. Hu, and B. Yi, J. Membr. Sci. 280, 148 (2006).

    Article  CAS  Google Scholar 

  17. S. Ren, G. Sun, Ch. Li, et al., J. Power Sources 157, 724 (2006).

    Article  CAS  Google Scholar 

  18. A. D’Epifanio, M. Assunta Navarra, F. Ch. Weise, et al., Chem. Mater. 22, 813 (2010).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  19. I. G. Wenten and Khoiruddin, J. Eng. Sci. Technol. 11, 916 (2016).

    Google Scholar 

  20. R. Singh and N. Hankins, Emerging Membrane Technology for Sustainable Water Treatment (Elsevier, Amsterdam, 2016).

    Google Scholar 

  21. J. Křivčík, D. Nedĕla, J. Hadrava, and L. Brožová, Desalin. Water Treat. 56, 3160 (2015).

    Google Scholar 

  22. K.-D. Kreuer, J. T. Hynes, J. P. Klinman, et al., Hydrogen-Transfer Reactions, Ed. by J. T. Hynes, J. P. Klinman, H. H. Limbach and R. L. Schowen (Wiley–VCH, Weinhem, 2007), vol. 1, p. 709.

  23. K. A. Mauritz and R. B. Moore, Chem. Rev. 104, 4535 (2004).

    Article  CAS  PubMed  Google Scholar 

  24. S. M. Ibrahim, E. H. Price, and R. A. Smith, Proc.—Electrochem. Soc., 83-6, 206 (1983).

    CAS  Google Scholar 

  25. M. A. Hickner, H. Ghassemi, Y. S. Kim, et al., Chem. Rev. 104, 4587 (2004).

    Article  CAS  PubMed  Google Scholar 

  26. S. Rabiej and A. Wlochowicz, Angew. Makromolek. Chem. 175 (2920), 81 (1990).

    Article  CAS  Google Scholar 

  27. D. V. Golubenko, P. A. Yurova, Yu. A. Karavanova, and I. A. Stenina, Inorg. Mater. 53, 1053 (2017).

    Article  CAS  Google Scholar 

  28. A. B. Yaroslavtsev, Yu. A. Karavanova, and E. Yu. Sa-fronova, Pet. Chem. 51, 473 (2011).

    Article  CAS  Google Scholar 

  29. V. V. Nikonenko, A. B. Yaroslavtsev, and G. Pourcelly, Ionic Interactions in Natural and Synthetic Macromolecules, Ed. by A. Ciferri and A. Perico (Wiley, Hoboken, NJ, 2012), p. 267.

    Google Scholar 

  30. V. V. Nikonenko, N. D. Pismenskaya, E. I. Belova, et al., Adv. Colloid Interface Sci. 160, 101 (2010).

    Article  CAS  PubMed  Google Scholar 

  31. D. V. Golubenko and A. B. Yaroslavtsev, Mendeleev Commun. 27, 572 (2017).

    Article  CAS  Google Scholar 

  32. I. A. Stenina and A. B. Yaroslavtsev, Inorg. Mater. 53, 253 (2017).

    Article  CAS  Google Scholar 

  33. N. Kononenko, V. Nikonenko, D. Grandeb, et al., Adv. Colloid Interface Sci. 246, 196 (2017).

    Article  CAS  PubMed  Google Scholar 

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ACKNOWLEDGMENTS

This work was supported by the Russian Science Foundation, project no. 16-13-00127.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    P. A. Yurova, I. A. Stenina & A. B. Yaroslavtsev

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  1. P. A. Yurova
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  2. I. A. Stenina
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  3. A. B. Yaroslavtsev
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Correspondence to I. A. Stenina.

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Translated by M. Timoshinina

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Yurova, P.A., Stenina, I.A. & Yaroslavtsev, A.B. A Comparative Study of the Transport Properties of Homogeneous and Heterogeneous Cation-Exchange Membranes Doped with Zirconia Modified with Phosphoric Acid Groups. Pet. Chem. 58, 1144–1153 (2018). https://doi.org/10.1134/S0965544118130108

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