Abstract
The melting point and enthalpy of fusion are refined for p-quaterphenyl (4P) and measured for the first time for its derivative with two terminal trimethylsilyl substituents (TMS-4P-TMS) by DSC method. The optical absorption spectra of 4P and TMS-4P-TMS solutions in toluene are measured at 25°C. Analysis of the absorption spectra shows the range within which aggregated solutions of the investigated substances exist. The shape of the absorption spectra of concentrated TMS-4P-TMS solutions indicates the J-aggregation of molecules occurs. It is found that the solubility of the TMS-4P-TMS derivative in toluene at room temperature is almost six times higher than that of p-quaterphenyl. Large single-crystal films and plates of the investigated compounds (up to 8 mm in size for 4P and up to 25 mm in size for TMS-4P-TMS) are obtained by growing them from solutions. Data on crystal growth of TMS-4P-TMS are reported for the first time.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
C. Wang, H. Dong, L. Jiang, and W. Hu, Chem. Soc. Rev. 47, 422 (2018).
V. A. Postnikov, Y. I. Odarchenko, A. V. Iovlev, et al., Cryst. Growth Des. 14, 1726 (2014).
L. G. Kudryashova, M. S. Kazantsev, and V. A. Postnikov, ACS Appl. Mater. Interfaces 8, 10088 (2016).
W. Ried and D. Freitag, Angew. Chem. 80, 932 (1968).
A. Piaggi, G. Lanzani, G. Bongiovanni, et al., Phys. Rev. B 56, 10133 (1997).
K. Al-Shamery, H.-G. Rubahn, and H. Sitter, Organic Nanostructures for Next Generation Devices (Springer, 2008).
M. Sparenberg, A. Zykov, P. Beyer, et al., Phys. Chem. Chem. Phys. 16, 26084 (2014).
B. Salekh and M. Teikh, Optics and Photonics. Principles and Applications (Intellekt, Dolgoprudnyi, 2012), Vol. 2 [in Russian].
B. M. Krasovitskii and B. M. Bolotin, Organic Luminophores (Khimiya, Moscow, 1984) [in Russian].
B. Birks, D. W. Fry, L. Costrell, and K. Kandiah, The Theory and Practice of Scintillation Counting (Pergamon, Oxford, 1964), p. 290.
R. Hirase, M. Ishihara, T. Katagiri, et al., Org. Electron. 15, 1481 (2014).
V. A. Postnikov, N. I. Sorokina, O. A. Alekseeva, A. A. Kulishov, R. I. Sokolnikov, M. S. Lyasnikova, V. V. Grebenev, O. V. Borshchev, M. S. Skorotecky, N. M. Surin, E. A. Svidchenko, S. A. Ponomarenko, and A. E. Voloshin, Crystallogr. Rep. 63, 819 (2018).
V. A. Postnikov, N. I. Sorokina, O. A. Alekseeva, V. V. Grebenev, M. S. Lyasnikova, O. V. Borshchev, N. M. Surin, E. A. Svidchenko, S. A. Ponomarenko, and A. E. Voloshin, Crystallogr. Rep. 63, 139 (2018).
O. D. Parashchuk, A. A. Mannanov, V. G. Konstantinov, et al., Adv. Funct. Mater. 28, 1800116 (2018).
A. P. Kreshkov, Fundamentals of Analytical Chemistry (Khimiya, Moscow, 1970), Vol. 3 [in Russian].
V. A. Postnikov and S. V. Chertopalov, Crystallogr. Rep. 60, 594 (2015).
J. Wasicki, M. Radomska, and R. Radomski, J. Therm. Anal. 25, 509 (1982).
K. Saito, T. Atake, and H. Chihara, J. Chem. Thermodyn. 17, 539 (1985).
J. C. Lindon, G. E. Tranter, and D. W. Koppenaal, Encyclopedia of Spectroscopy and Spectrometry, 3rd ed. (Elsevier, Amsterdam, 2017), Vol. 1, p. 509.
V. D. Aleksandrov and V. A. Postnikov, Russ. J. Phys. Chem. A 78, 296 (2004).
Funding
This work was supported by the Russian Foundation for Basic Research, project no. 16-02-00931-a. It was performed on equipment at the shared resource center of the Federal Research Center of Crystallography and Photonics, Russian Academy of Sciences.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by D. Terpilovskaya
Rights and permissions
About this article
Cite this article
Postnikov, V.A., Lyasnikova, M.S., Kulishov, A.A. et al. Solubility and Crystal Growth of p-Quaterphenyl and Its Derivative with Trimethylsilyl Terminal Substituents. Russ. J. Phys. Chem. 93, 1741–1746 (2019). https://doi.org/10.1134/S0036024419090176
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024419090176