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Oxidation of benzyl alcohol by K2FeO4 to benzaldehyde over zeolites

  • Chemical Kinetics and Catalysis
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Abstract

A novel and green procedure for benzaldehyde synthesis by potassium ferrate oxidation of benzyl alcohol employing zeolite catalysts was studied. The prepared oxidant was characterized by SEM and XRD. The catalytic activity of various solid catalysts was studied using benzyl alcohol as a model compound. USY was found to be a very efficient catalyst for this particular oxidation process. Benzaldehyde yields up to 96.0% could be obtained at the following optimal conditions: 0.2 mL of benzyl alcohol, 4 mmol of K2FeO4, 0.5 g of USY zeolite; 20 mL of cyclohexene, 0.3 mL of acetic acid (36 wt %), 30°C temperature, 4 h reaction time.

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Authors and Affiliations

  1. Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing, Heilongjing, 163318, China

    Yuan-Yuan Wang & Hua Song

  2. Key Laboratory of Cancer Prevention and Treatment of Heilongjiang Province, Mudanjiang Medical University, Mudanjiang, Heilongjing, 157011, China

    Hua-Lin Song & Zai-Shun Jin

Authors
  1. Yuan-Yuan Wang
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  2. Hua Song
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  3. Hua-Lin Song
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  4. Zai-Shun Jin
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Correspondence to Hua Song.

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Wang, YY., Song, H., Song, HL. et al. Oxidation of benzyl alcohol by K2FeO4 to benzaldehyde over zeolites. Russ. J. Phys. Chem. 90, 1931–1935 (2016). https://doi.org/10.1134/S0036024416100290

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  • DOI: https://doi.org/10.1134/S0036024416100290

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