Skip to main content
SpringerLink
Log in

Kinetics and mechanism of olefin catalytic hydroalumination by organoaluminum compounds

  • Chemical Kinetics and Catalysis
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The complex reaction mechanism of α-olefin catalytic hydroalumination by alkylalanes is investigated via mathematical modeling that involves plotting the kinetic models for the individual reactions that make up a complex system and a separate study of their principles. Kinetic parameters of olefin catalytic hydroalumination are estimated. Activation energies of the possible steps of the schemes of complex reaction mechanisms are compared and possible reaction pathways are determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. O. Terent’ev, N. S. Borisova, E. M. Khamitov, Yu. S. Zimin, and A. G. Mustafin, Russ. J. Phys. Chem. A 88, 2068 (2014).

    Article  Google Scholar 

  2. Direct and Inverse Problems in Chemical Kinetics, Ed. by V. I. Bykov (Nauka, Novosibirsk, 1993) [in Russian].

  3. A. Yu. Putin, E. Yu. Bychkova, K. V. Trunilina, A. Yu. Zakgeim, E. A. Katsman, O. N. Shishilov, N. S. Akhmadullina, I. V. Oshanina, O. N. Temkin, and L. G. Bruk, Russ. J. Phys. Chem. A 89, 359 (2015).

    Article  CAS  Google Scholar 

  4. S. I. Spivak and A. S. Ismagilova, Dokl. Phys. Chem. 455, 53 (2014).

    Article  CAS  Google Scholar 

  5. L. F. Nurislamova and I. M. Gubaidullin, Vychisl. Metody Program. 15, 685 (2014).

    Google Scholar 

  6. L. Beranek, Adv. Catal. 24, 1 (1975).

    CAS  Google Scholar 

  7. L. V. Parfenova, R. F. Vil’danova, S. V. Pechatkina, et al., J. Organomet. Chem. 692, 3424 (2007).

    Article  CAS  Google Scholar 

  8. K. F. Koledina, Extended Abstract of Cand. Sci. (Phys. Math.) Dissertation (Bashkir. State Univ., Ufa, 2011).

    Google Scholar 

  9. E. Y. Pankratyev, T. V. Tyumkina, L. V. Parfenova, et al., Organometallics 28, 968 (2009).

    Article  CAS  Google Scholar 

  10. K. F. Koledina and I. M. Gubaidullin, Nauka Obrazov., No. 7, 385 (2013).

    Google Scholar 

  11. A. B. Alshin, E. A. Alshina, N. N. Kalitkin, and A. B. Koryagina, Comput. Math. Math. Phys. 46, 1320 (2006).

    Article  Google Scholar 

  12. I. Gubaydullin, K. Koledina, and L. Sayfullina, Eng. J. 18, 13 (2014).

    Article  Google Scholar 

  13. I. M. Gubaidullin, K. F. Koledina, and Yu. B. Lind, ParKin Software for Solving of Inverse Problems of Chemical Kinetics Using Parallel Calculations, Registration Certificate No. 17868 (2012).

  14. A. V. Novichkova, Yu. O. Bobreneva, I. M. Gubaidullin, and K. F. Koledina, INTKIN Software for Calculation of Intervals of Uncertainty of Kinetic Parameters. Registration Certificate No. 19951 (2014); Nauka Obrazov. 1 (2), 52 (2014).

    Google Scholar 

  15. I. M. Gubaidullin, K. F. Koledina, and Yu. B. Lind, Nauka Obrazov., No. 06, 10 (2011).

    Google Scholar 

  16. A. V. Novichkova, Yu. O. Bobreneva, I. M. Gubaidullin, and K. F. Koledina, Elektrotekh. Inform. Kompleksy Sist. 10 (3), 55 (2014).

    Google Scholar 

  17. I. M. Gubaidullin, K. F. Koledina, and R. R. Safin, Sist. Upravl. Inform. Tekhnol. 58 (4), 10 (2014).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa, 450075, Russia

    K. F. Koledina & I. M. Gubaidullin

Authors
  1. K. F. Koledina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. M. Gubaidullin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to K. F. Koledina.

Additional information

Original Russian Text © K.F. Koledina, I.M. Gubaidullin, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 5, pp. 671–678.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Koledina, K.F., Gubaidullin, I.M. Kinetics and mechanism of olefin catalytic hydroalumination by organoaluminum compounds. Russ. J. Phys. Chem. 90, 914–921 (2016). https://doi.org/10.1134/S0036024416050186

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024416050186

Keywords

Search

Navigation