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Density, partial, and excess volumes of solutions of methacrylic acid in organic solvents at 293 K

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Abstract

The densities of solutions of methacrylic acid in acetonitrile, benzene, hexane, 1,2-dichloroethane, and acetic acid at a temperature of 293 K and atmospheric pressure are determined by means of pycnometry. The values of the excess molar volume for the studied systems and those of the partial molar volumes of the components are calculated. It is found that the excess molar volume of binary systems of methacrylic acid with benzene, hexane, 1,2-dichloroethane, and acetic acid is positive over the range of concentrations and is negative in the methacrylic acid-acetonitrile system.

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Authors and Affiliations

  1. Lviv National Polytechnical University, Lviv, 79000, Ukraine

    V. V. Sergeev & Yu. Ya. Van-Chin-Syan

Authors
  1. V. V. Sergeev
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  2. Yu. Ya. Van-Chin-Syan
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Correspondence to V. V. Sergeev.

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Original Russian Text © V.V. Sergeev, Yu.Ya. Van-Chin-Syan, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 3, pp. 409–413.

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Sergeev, V.V., Van-Chin-Syan, Y.Y. Density, partial, and excess volumes of solutions of methacrylic acid in organic solvents at 293 K. Russ. J. Phys. Chem. 89, 406–410 (2015). https://doi.org/10.1134/S0036024415030279

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  • DOI: https://doi.org/10.1134/S0036024415030279

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