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Calculating the thermodynamic characteristics of the stepwise transesterification of simple triglycerides

  • Chemical Thermodynamics and Thermochemistry
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Abstract

Thermodynamic data for mono- and diglycerides of palmitic, oleic, and linoleic fatty acids participating in the stepwise transesterification reaction of the corresponding simple triglycerides in methanol are calculated. The obtained thermodynamic parameters allow us to calculate the chemical equilibrium and the equilibrium composition of the products of the stepwise transesterification reaction of fatty acid triglycerides with supercritical methanol.

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References

  1. E. C. Petrou and C. P. Pappis, Energy Fuels 23, 1055 (2009).

    Article  CAS  Google Scholar 

  2. E. Lotero, Y. Liu, D. E. Lorez, et al., Ind. Eng. Chem. Res. 44, 5353 (2005).

    Article  CAS  Google Scholar 

  3. F. Er. Ma and M. A. Hanna, Bioresour. Technol. 70, 1 (1999).

    Article  CAS  Google Scholar 

  4. C. V. McHeff, L. C. McHeff, B. Yan, et al., Appl. Catal. A: Gen. 343, 39 (2008).

    Article  Google Scholar 

  5. M. D. Serio, R. Tesser, L. Pengmei, and E. Santacesaria, Energy Fuels 22, 207 (2008).

    Article  Google Scholar 

  6. A. Brito, M. E. Borges, M. Garin, and A. Hernandez, Energy Fuels 23, 2952 (2009).

    Article  CAS  Google Scholar 

  7. S. Saka and D. Kusdiana, Fuel 80, 225 (2001).

    Article  CAS  Google Scholar 

  8. D. Kusdiana and S. Saka, Fuel 80, 693 (2001).

    Article  CAS  Google Scholar 

  9. D. Kusdiana, S. Saka, Bioresour. Technol. 91, 289 (2004).

    Article  CAS  Google Scholar 

  10. E. Song, J. Lim, H. Lee, and Y. Lee, J. Supercrit. Fluids 44, 356 (2008).

    Article  CAS  Google Scholar 

  11. M. M. Gui, K. T. Lee, and S. Bhatia, J. Supercrit. Fluids 49, 286 (2009).

    Article  CAS  Google Scholar 

  12. L. Wang and J. Yang, Fuel 86, 328 (2007).

    Article  CAS  Google Scholar 

  13. V. F. Marulanda, G. Anitescu, and L. L. Tavlarides, Energy Fuels 24, 253 (2010).

    Article  CAS  Google Scholar 

  14. C. Bertoldi, D. Siva, J. P. Bernardon, et al., Energy Fuels 23, 165 (2009).

    Article  Google Scholar 

  15. A. Demirbas, Progress Energy Combust. Sci. 31, 466 (2005).

    Article  CAS  Google Scholar 

  16. D. A. Stepanov, A. Ermakova, and V. I. Anikeev, Russ. J. Phys. Chem. A 85, 21 (2011).

    Article  CAS  Google Scholar 

  17. V. I. Anikeev, D. A. Stepanov, and A. Ermakova, Zh. Fiz. Khim. 85, 1449 (2011) [Russ. J. Phys. Chem. A 85, 1336 (2011)].

    Google Scholar 

  18. H. Noureddini and D. Zhu, J. Am. Oil Chem. Soc. 74, 1157 (1997).

    Google Scholar 

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. I. Anikeev, D. A. Stepanov & A. Ermakova

Authors
  1. V. I. Anikeev
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  2. D. A. Stepanov
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  3. A. Ermakova
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Original Russian Text © V.I. Anikeev, D.A. Stepanov, A. Ermakova, 2011, published in Zhurnal Fizicheskoi Khimii, 2011, Vol. 85, No. 12, pp. 2231–2237.

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Anikeev, V.I., Stepanov, D.A. & Ermakova, A. Calculating the thermodynamic characteristics of the stepwise transesterification of simple triglycerides. Russ. J. Phys. Chem. 85, 2082–2087 (2011). https://doi.org/10.1134/S0036024411120028

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  • DOI: https://doi.org/10.1134/S0036024411120028

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