Abstract
The Gibbs energies of transfer of glycine from water into water-dimethyl sulfoxide mixtures were determined at 298 K by measurements of substance distribution between immiscible phases. The enthalpy and entropy contributions to ΔG° of glycinate ion resolvation in water-dimethyl sulfoxide solvents were analyzed. The destabilization of glycinate ion was found to be largely determined by the energy component mainly. There was a correlation between the enthalpies of transfer of glycinate ion and the autoprotolysis constants of water-dimethyl sulfoxide solvents. The suggestion was made that changes in the Gibbs energies of glycinate ion resolvation in water-dimethyl sulfoxide and water-alcohol mixtures were largely determined by changes in the acid-base properties of the solvents.
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Original Russian Text © Zh.F. Gesse, V.A. Isaeva, V.A. Sharnin, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 2, pp. 385–387.
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Gesse, Z.F., Isaeva, V.A. & Sharnin, V.A. The gibbs energies of transfer of glycine and glycinate ion from water into water-dimethyl sulfoxide mixtures. Russ. J. Phys. Chem. 84, 329–331 (2010). https://doi.org/10.1134/S0036024410020299
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DOI: https://doi.org/10.1134/S0036024410020299