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The thermodynamics of benzene adsorption on carbon obtained by the pyrolysis of hypercrosslinked polystyrene

  • Physical Chemistry of Surface Phenomena
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Abstract

The Glukauf chromatography method was used to study the adsorption of benzene on a microporous carbon material prepared by the pyrolysis of hypercrosslinked polystyrene. The thermodynamic characteristics of adsorption were determined as functions of the degree of pore filling. Over the range of relative pressures studied (<0.005), adsorption was shown to occur in ultramicropores by the mechanism of primary filling without condensed phase formation.

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Correspondence to L. D. Asnin.

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Original Russian Text © L.D. Asnin, V.A. Davankov, A.V. Pastukhov, K. Kaczmarski, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 7, pp. 1356–1359.

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Asnin, L.D., Davankov, V.A., Pastukhov, A.V. et al. The thermodynamics of benzene adsorption on carbon obtained by the pyrolysis of hypercrosslinked polystyrene. Russ. J. Phys. Chem. 83, 1204–1207 (2009). https://doi.org/10.1134/S0036024409070279

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  • DOI: https://doi.org/10.1134/S0036024409070279

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