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Regularities of change in the structural parameters of EuLnCuS3 (Ln = La–Nd, Sm, Gd, Ho)

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Regularities of change in the structural parameters of EuLnCuS3 (Ln = La–Nd, Sm, Gd, Ho) at an annealing temperature of 970 and 1170 K have been established. A decrease in the Ln3+ ionic radius results in the consecutive change of structural types (STs) for the compounds: α-EuLnCuS3 (Ln = La, Ce, Pr, Nd; BaLaCuS3 ST) → β-EuLnCuS3 (Ln = Ce, Pr, Nd; Ba2MnS3 ST) → γ-EuLnCuS3 (Ln = Sm, Gd, Ho; Eu2CuS3ST). The change of structural types for EuLnCuS3 leads to a jump-like change in their unit cell parameters and the transformation of coordination polyhedra shaped as a one-capped trigonal prism LnS7 (α and β phases) into an octahedron LnS6 (γ phases). The appearance of morphotropic changes correlates with the tetrad effect.

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References

  1. L. Koscielski and J. A. Ibers, Acta Crystallogr., Sect. E 68, i52 (2012).

    Article  CAS  Google Scholar 

  2. F. Furuuchi and Y. Hinatsu, J. Phys.: Condens. Matter 16, 5503 (2004).

    Google Scholar 

  3. O. V. Andreev and A. V. Ruseikina, Vestn. Tyumen. Gos. Univ., No. 3, 221 (2010).

    Google Scholar 

  4. A. V. Ruseikina, L. A. Solov’ev, M. S. Molokeev, and O. V. Andreev, Russ. J. Inorg. Chem. 57, 79 (2012).

    Article  CAS  Google Scholar 

  5. A. V. Ruseikina, L. A. Solov’ev, and O. V. Andreev, Russ. J. Inorg. Chem. 57, 574 (2012).

    Article  CAS  Google Scholar 

  6. A. V. Ruseikina, L. A. Solov’ev, and O. V. Andreev, Russ. J. Inorg. Chem. 58, 1231 (2013).

    Article  CAS  Google Scholar 

  7. A. V. Ruseikina, L. A. Solovyev, O. V. Andreev, and A. A. Kislitsyn, Russ. J. Inorg. Chem. 59, 1109 (2014).

    Article  CAS  Google Scholar 

  8. Yu. A. Murashko, A. V. Ruseikina, A. A. Kislitsyn, and O. V. Andreev, Inorg. Mater. 51, 1213 (2015).

    Article  CAS  Google Scholar 

  9. A. V. Ruseikina, Zh. A. Demchuk, and A. A. Kislitsyn, Vestn. Tyumen. Gos. Univ., No. 5, 19 (2012).

    Google Scholar 

  10. T. Brennan and J. A. Ibers, J. Solid State Chem. 97, 377 (1992).

    Article  CAS  Google Scholar 

  11. P. Lemoine, D. Carre, and M. Guittard, Acta Crystallogr., Sect. C 42, 390 (1986).

    Article  Google Scholar 

  12. A. V. Ruseikina, Russ. J. Inorg. Chem. 61, 1403 (2016).

    Article  CAS  Google Scholar 

  13. D. Chareev, E. Osadchii, T. Kuzmicheva, et al., CrystEngComm 15, 1989 (2013).

    Article  CAS  Google Scholar 

  14. K. Brandenburg, “DIAMOND,” Visual Crystal Structure Information System CRUSTAL IMPACT, Postfach, 1251, D-53002 Boon.

  15. A. V. Ruseikina, L. A. Solov’ev, and O. V. Andreev, Russ. J. Inorg. Chem. 59, 169 (2014).

    Google Scholar 

  16. A. V. Ruseikina and Zh. A. Demchuk, Russ. J. Inorg. Chem. 62, 27 (2017).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Tyumen State University, ul. Volodarskogo 6, Tyumen, 625003, Russia

    A. V. Ruseikina & O. V. Andreev

Authors
  1. A. V. Ruseikina
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  2. O. V. Andreev
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Correspondence to A. V. Ruseikina.

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Original Russian Text © A.V. Ruseikina, O.V. Andreev, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 2, pp. 165–172.

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Ruseikina, A.V., Andreev, O.V. Regularities of change in the structural parameters of EuLnCuS3 (Ln = La–Nd, Sm, Gd, Ho). Russ. J. Inorg. Chem. 62, 160–167 (2017). https://doi.org/10.1134/S0036023617020140

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